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Limits of isomorphous substitution of molecules in normal paraffins as a function of temperature

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Abstract

The limits of isomorphous substitutions and the symmetry of synthetic binary solid solutions of paraffins CnH2n+2 with n=17–24 have been studied by X-ray diffraction and thermal X-ray diffraction. Principles of isomorphous substitutions of paraffin molecules are suggested which take into consideration the length (n), the symmetry (parity of n), and the intensity of thermal rotational motion of component molecules.

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Authors
  1. S. K. Filatov
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  2. E. N. Kotelnikova
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Additional information

St. Petersburg State University. Translated fromZhurnal Strukturnoi Khimii Vol. 34, No. 4, pp. 117–127, July–August, 1993.

Translated by T. Yudanova

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Filatov, S.K., Kotelnikova, E.N. Limits of isomorphous substitution of molecules in normal paraffins as a function of temperature. J Struct Chem 34, 593–601 (1994). https://doi.org/10.1007/BF00753531

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  • DOI: https://doi.org/10.1007/BF00753531

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