Abstract
The infrared absorption spectra of water in the water-dioxane and water-dimethylsulfoxide systems have been investigated in a wide range of concentrations. Absorption bands of differen: forms of water present in solution have been identified. The state of internal water in aqueous microregions in both systems is characterized by increased stability. It is proposed that the specific state of the internal water of microregions is the motive force of the microlayering process hindering its ransition into ordinary macrolayering. Consecutive microlayering stages at varying concentrations of the nonelectrolyte are considered. The behavior of protein molecules in different microlayering solverts has been studied.
Similar content being viewed by others
References
B. Z. Gorbunov and Yu. I. Naberukhin,Zh. Struk. Khim.,16, 816–825 (1975).
V. I. Korsunsky and Yu. I. Naberukhin,Zh. Struk. Khim.,18, 587–603 (1977).
N. V. Rovnov, A. P. Zhukovsky, S. V. Sorvin, and L. N. Petrov, in:Abstracts of the 10the International Conference “Surface Forces”, Moscow (1992), p. 82.
Yu. A. Efimov and Yu. I. Naberukhin,Molecular Physics,33, 779–792 (1977).
Additional information
St. Petersburg State University. Translated fromZhurnal Struktumoi Khimii, Vol. 34, No. 4, pp. 83–88, July–August, 1993.
Translated by L. Smolina
Rights and permissions
About this article
Cite this article
Zhukovsky, A.P., Rovnov, N.V. & Zhukovsky, M.A. Comparative study of the structure of microlayering water-dioxane and water-dimethylsulfoxide solutions. J Struct Chem 34, 562–566 (1994). https://doi.org/10.1007/BF00753526
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00753526