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Crystal structure of copper(I) chloride π-complexes with diallylamine: (C6H12N)2Cu7Cl9·H2O and 2CuCl·C6H11N

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Abstract

For the first time we have synthesized and studied by X-ray structural analysis two novel copper(I) chloride π-complexes with diallylamine (DAA): [H(DAA)]2Cu7Cl9·H2O (D) and 2CuCl·DAA (E). Compound D is isostructural to the complex [H(DAA)]2Cu7Br9·H2O studied earlier: space group Pnam, a=15.934(8), b=14.817(6), c=11.368(6) Å, V=2684(4) Å3, and Z=4 for [(C6H12N)2 Cu7Cl9·H2O]. Crystals E are triclinic: space group P1, a=7.373(2), b=9.743(4), c=11.351(8) Å, α=84.05(4), β=101.26(4), γ=103.31(3)°, V=914(2) Å3, and Z=2 for [Cu4Cl4·(C6H11N)2]. The layers of the structure are formed by combining the armchair-shaped cycles Cu4Cl4 via the tridentate DAA molecules.

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Authors
  1. V. V. Olijnik
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  2. M. G. Myskiv
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  3. V. K. Pecharskii
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Additional information

I. Franko Lvov State University, Ukrainian Academy of Sciences. Translated fromZhurnal Strukturnoi Khimii, Vol. 34, No. 6, pp. 43–48, November–December, 1993.

Translated by T. Yudanova

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Olijnik, V.V., Myskiv, M.G. & Pecharskii, V.K. Crystal structure of copper(I) chloride π-complexes with diallylamine: (C6H12N)2Cu7Cl9·H2O and 2CuCl·C6H11N. J Struct Chem 34, 865–871 (1993). https://doi.org/10.1007/BF00752859

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  • DOI: https://doi.org/10.1007/BF00752859

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