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Studies on the formation and thermal properties of manganese phosphate coatings and hureaulite by means of conversion electron and transmission Mössbauer spectrometry

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Abstract

The chemical states of iron species, produced in manganese phosphate coatings by the immersion of steel in a manganese phosphate bath, were analysed with the help of conversion electron and conventional transmission Mössbauer spectrometry (CEMS and TMS). The modifications of hureaulite by the variation of iron to manganese ratio are discussed with regard to the growth of manganese phosphate coatings. The thermal properties of manganese phosphate coatings and synthetic hureaulite were also investigated by means of differential thermal analysis and the composition analysis of thermal products.

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Authors and Affiliations

  1. Faculty of Engineering, The University of Tokyo, Hongo 7-3-1, Bunkyo-ku, 113, Tokyo, Japan

    Kiyoshi Nomura & Yusuke Ujihira

Authors
  1. Kiyoshi Nomura
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  2. Yusuke Ujihira
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Nomura, K., Ujihira, Y. Studies on the formation and thermal properties of manganese phosphate coatings and hureaulite by means of conversion electron and transmission Mössbauer spectrometry. J Mater Sci 17, 3437–3444 (1982). https://doi.org/10.1007/BF00752189

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  • DOI: https://doi.org/10.1007/BF00752189

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