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Quantum yield spectra of vanadium in tetrahedral [VO4]3− complexes

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Conclusions

Studies of VL2,3 quantum yield spectra and analysis of theoretical and experimental data were used to give information on the processes proceeding during the emission and absorption of the X-ray VL-radiation. It is very probable that the X-ray L3-absorption processes in compounds where the 3d-metal has the highest valence proceed in the presence of an additional electron on one of the vacant orbitals (for tetrahedral complexes on the 2e-MO). This assumption can confirm the hypothesis on the reemissional transitions and explain the energy divergence between the VL-emission and absorption spectra.

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Literature Cited

  1. J. A. Baglio and G. Gashurov, Acta Crystallogr.,24, 292 (1968).

    Google Scholar 

  2. N. Krishamachari and C. Calvo, Can. J. Chem.,49, No. 10, 1629 (1971).

    Google Scholar 

  3. R. Gopal and C. Calvo, Z. Kristallographie, B137, No. 1, 67 (1973).

    Google Scholar 

  4. A. Durif, Acta Crystallogr.,12, No. 9, 420 (1959).

    Google Scholar 

  5. V. D. Zhuravlev, Candidate's Dissertation, Sverdlovsk (1981).

  6. V. R. Galakhov, V. M. Cherkashenko, M. Ya. Hodos, et al., J. Electr. Spectr. Relat. Phen.,35, 87 (1985).

    Google Scholar 

  7. V. M. Cherkashenko, V. R. Galakhov, and É. Z. Kurmaev, Zh. Strukt. Khim.,27, No. 4, 185 (1986).

    Google Scholar 

  8. I. M. Curelaru and P. O. Nilsson, J. Phys. Chem. Solids,40, 887 (1979).

    Google Scholar 

  9. N. I. Lazukova, V. A. Gubanov, M. P. Butsman, et al., Zh. Strukt. Khim.,21, 41 (1980).

    Google Scholar 

  10. E. Z. Kurmaev, V. M. Cherkashenko, and V. A. Gubanov, J. Electr. Spectr. Relat. Phen.,16, 455 (1979).

    Google Scholar 

  11. V. A. Gubanov, D. E. Ellis, and A. A. Fotiev, J. Solid State Chem.,21, 303 (1977).

    Google Scholar 

  12. F. W. Kutzler, D. E. Ellis, D. J. Lam, et al., Phys. Rev. B,29, No. 2, 1008 (1984).

    Google Scholar 

  13. V. I. Anisimov, E. Z. Kurmaev, and V. A. Gubanov, J. Electr. Spectr. Relat. Phen.,22, 277 (1981).

    Google Scholar 

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Authors
  1. V. P. Galakhov
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  2. V. M. Cherkashenko
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  3. Z. Z. Kurmaev
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  4. M. Ya. Khodos
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Additional information

Institute of Physics of Metals, Ural Branch Academy Sciences of the USSR. Translated from Zhurnal Strukturnoi Khimii, Vol. 29, No. 1, pp. 81–86, January–February, 1988.

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Galakhov, V.P., Cherkashenko, V.M., Kurmaev, Z.Z. et al. Quantum yield spectra of vanadium in tetrahedral [VO4]3− complexes. J Struct Chem 29, 69–73 (1988). https://doi.org/10.1007/BF00750179

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  • DOI: https://doi.org/10.1007/BF00750179

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