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The agronomic effectiveness of reactive rock phosphate, partially acidulated rock phosphate and monocalcium phosphate in soils of different pH

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Abstract

The initial and residual fertilizer effectiveness of North Carolina RP (rock phosphate), monocalcium phosphate and partially acidulated RP (made from North Carolina RP at 30% acidulation), both granulated and non-granulated, were measured in a glasshouse experiment. Triticale (xTriticosecale) was grown for 30 days on a soil that had been adjusted to three pH values (4.2, 5.2 and 6.2). Two crops were grown with a six month interval between crops. The effectiveness of the different fertilizers was compared using relationships between (1) yield of dried tops and the amount of P applied and (2) P content (P concentration in tissue multiplied by yield) and the amount of P applied. For the first crop, relative effectiveness (RE) of the fertilizers was calculated relative to granulated monocalcium phosphate, the most effective fertilizer. Monocalcium phosphate was not applied to the second crop, so relative residual effectiveness (RRE) was estimated for each fertilizer relative to the residual effectiveness of granulated monocalcium phosphate.

The relative effectiveness of granulated monocalcium phosphate (band application) was greater (RE = 1.00) than of North Carolina RP (0.01–0.02) and partially acidulated RP (0.45–0.76) for all three soil pH values for the first crop. Granulation and band application increased the effectiveness of monocalcium phosphate and partially acidulated RP, but reduced the effectiveness of North Carolina RP. Both non-granulated monocalcium phosphate and partially acidulated RP were less effective than granulated partially acidulated RP for both crops. For the second crop granulated monocalcium phosphate was most effective and the RRE of non-granulated partially acidulated RP (0.16–0.32) and North Carolina RP (0.19–0.28) was greater than for non-granulated monocalcium phosphate (0.12). For the more acidic soil the RE of non-granulated North Carolina RP was four times higher than for the high pH soil for the first crop and 60% higher for the second crop, but it was still poorly effective relative to granulated monocalcium phosphate. Granulated North Carolina RP was least effective among all the fertilizers for all soil pH values and for both crops.

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References

  1. AOAC (1975) Official Methods of Analysis. 12th Edn. Assoc Off Agri Chem: Washington DC

    Google Scholar 

  2. Ashby DI, Fenster WE and Attoe OJ (1966) Effect of partial acidulation and elemental sulfur on availability of phosphorus in rock phosphate. Agron J 58: 621–625

    Google Scholar 

  3. Barrow NJ and Campbell NA (1972) Methods of measuring the residual values of fertilizers. Aust J Exp Agric Anim Husb 12: 502–510

    Google Scholar 

  4. Black CA and Scott CO (1956) Fertilizer evaluation. I. Fundamental principles. Soil Sci Soc Am Proc 20: 176–179

    Google Scholar 

  5. Bolland MDA, Glencross RN, Gilkes RJ and Kumar V (1992) Effectiveness of partially acidulated rock phosphate and fused calcium-magnesium phosphate compared with superphosphate. Fert Res 32: 169–183

    Google Scholar 

  6. Bolland MDA and Gilkes RJ (1990) Rock phosphates are not effective fertilizers in Western Australian soils: a review of one hundred years of research. Fert Res 22: 79–95

    Google Scholar 

  7. Chien SH and Hammond LL (1978) A simple chemical method for evaluating the agronomic potentially of granulated phosphate rock. Soil Sci Soc Am J 42: 615–617

    Google Scholar 

  8. Chien SH and Hammond LL (1988) Agronomic evaluation of partially acidulated phosphate rocks in the tropics-IFDC's experience. Paper series (International Fertilizer Development Centre) IFDC-P-7

  9. Davies GR (1984) Comparison of water-insoluble phosphate fertilizers with superphosphate - a review. J Sci Food Agric 35: 265–271

    Google Scholar 

  10. Engelstad OP, Jugsujinda A and De Datta SK (1974) Response by flooded rice to phosphate rocks varying in citrate solubility. Soil Sci Soc Am J 38: 524–529

    Google Scholar 

  11. Engelstad OP and Terman GL (1980) Agronomic effectiveness of phosphate fertilizers, In: Khasawneh FE, Sample EC and Kamprath EJ (eds) The Role of Phosphorus in Agriculture, pp 311–332. Am Soc Agron. Madison, USA

    Google Scholar 

  12. Garbouchev IP (1981) The manufacture and agronomic efficiency of a partially acidulated phosphate rock fertilizer. Soil Sci Soc Am J 45: 970–974

    Google Scholar 

  13. Genstat 5 Committee (P.W. Payne, Chairman) (1988) Genstat 5 Reference manual. Oxford Science Publication

  14. Gillman GP and Sumpter EA (1986) Modification to the compulsive exchange method for measuring exchange characteristics of soils. Aust J Soil Res 24: 61–66

    Google Scholar 

  15. Gregg PEH, Bolan NS, Hedley MJ and White RE (1988) Reactive phosphate rocks potential as a direct use fertilizer and as a component of other phosphorus fertilizers. In: Proc. Phosphorus Symposium, pp 6-20. Pretoria

  16. Hammond LL, Chien SH and Polo JR (1980) Phosphorus availability from partially acidulation of two phosphate rocks. Fert Res 1: 37–49

    Google Scholar 

  17. Hammond LL, Chien SH and Mokwunye AU (1986) Agronomic value of unacidulated phosphate rocks indigenous to the tropics. Adv Agron 40: 89–140

    Google Scholar 

  18. Kanabo IAK and Gilkes RJ (1987) The role of soil pH in the dissolution of phosphate rock fertilizers. Fert Res 12: 165–174

    Google Scholar 

  19. Kendall M and Stuart A (1987) The Advanced Theory of Statistics Vol 1. Distribution Theory. 5th Edn, pp 320–344. Charles Griffin & Com Ltd: London

    Google Scholar 

  20. LeMare PH (1991) Rock phosphate in agriculture. Exp Agric 27: 413–422

    Google Scholar 

  21. Lutz JA Jr (1973) Effect of partially acidulated rock phosphate and concentrated superphosphate as a source of phosphorus for corn. Agron J 63: 919–922

    Google Scholar 

  22. Lutz JA Jr (1971) Comparison of partially acidulated rock phosphate and concentrated superphosphate as sources of phosphorus for corn. Agron J 63: 919–922

    Google Scholar 

  23. Mackay AD and Syers JK (1986) Effect of phosphate, calcium and pH on the dissolution of a phosphate rock in soil. Fert Res 10: 175–184

    Google Scholar 

  24. McLean EO and Wheeler RW (1964) Partially acidulated rock phosphate as a source of phosphorus to plants: I. Growth chamber studies. Soil Sci Soc Am Proc 28: 545–550

    Google Scholar 

  25. McLean EO, Wheeler RW and Watson JD (1965) Partially acidulated rock phosphate as a source of phosphorus to plants: II. Growth chamber and field corn studies. Soil Sci Soc Am Proc 29: 625–629

    Google Scholar 

  26. McLean EO and Balam BS (1967) Partially acidulated rock phosphate as a source of phosphorus to plants: III. Uptake of corn from soils of different calcium status. Soil Sci Soc Am Proc 31: 811–814

    Google Scholar 

  27. McLean EO and Logan TJ (1970) Source of phosphorus for plant grown in soils with differing phosphorus fixation tendencies. Soil Sci Soc Am Proc 34: 907–911

    Google Scholar 

  28. Mokwunye AU and Chien SH (1980) Reactions of partially acidulated phosphate rock with soils from the tropics. Soil Sci Soc Am J 44: 477–482

    Google Scholar 

  29. Naidu R, Syers JK, Tillman RW and Kirkman JH (1990) Effect of liming on phosphate sorption by acid soils. J Soil Sci 41: 163–175

    Google Scholar 

  30. Northcote KH (1979) A factual key for the recognition of Australian soils. 4th Edition. Rellim tech publ: Glenside, South Australia

    Google Scholar 

  31. Ozanne PG and Shaw TC (1967) Phosphate sorption by soils as a measure of phosphate requirement for pasture growth. Aust J Agric Res 18: 601–612

    Google Scholar 

  32. Palmer B and Gilkes RJ (1982) Agronomic evaluation of calcined Christmas Island iron-aluminium phosphate fertilizers. In: Pushparajah E and Sharifuddin AH (eds) Proc Phos Pot Tropic Conf, Kuala Lumpur, pp 495–507. Malay Soc Soil Sci: Malaysia

    Google Scholar 

  33. Palmer B, Bolland MDA and Gilkes RJ (1979) A reevaluation of the effectiveness of calcined Christmas Island C-grade rock phosphate. Aust J Exp Agric Anim Husb 19: 605 - 610.

    Google Scholar 

  34. Rajan SSS (1982) Availability to plants of phosphate from “biosupers” and partially acidulated phosphate rock. NZ J Agric Res 25: 355–361

    Google Scholar 

  35. Rajan SSS (1985a) Partial acidulation of an “unground” phosphate rock: I. Preparation and characteristics. Fert Res 8: 147–155

    Google Scholar 

  36. Rajan SSS (1985b) Partial acidulation of an “unground” phosphate rock: II. Plant availability of phosphate. Fert Res 8: 219–229

    Google Scholar 

  37. Sale PWG, Friesen DK and Blair GJ (1991) Long-term greenhouse evaluation of partially acidulated phosphate rock fertilizers. III. Agronomic effectiveness relative to single superphosphate. Fert Res 29: 295–307

    Google Scholar 

  38. Snedecor GW and Cochran WG (1976) Statistical methods, pp 432–436. The Iowa State University Press: Ames, Iowa, USA

    Google Scholar 

  39. Stephen RC (1983) Agronomic values of phosphate rocks partially acidulated with phosphoric acid. Proc 19th Tech Conf NZ Fertilizer Manufacturers' Research Association, pp 267-279

  40. Terman GL, Killmer VJ and Allen SE (1969) Reactivity of phosphate rocks with acids in relation to effectiveness for crop. Phosphorus Agric 54: 1–9

    Google Scholar 

  41. Terman GL and Allen SE (1967) Response to corn of phosphorus in underacidulated phosphate rock and rocksuperphosphate fertilizers. J Agric Food, Chem 15: 354–358

    Google Scholar 

  42. Xie RJ and Mackenzie AF (1990) Mechanism of pH decrement in three temperate soils treated with phosphate. Soil Sci 150: 602–612

    Google Scholar 

  43. Yeomans JC and Bremner JM (1988) A rapid and precise method for routine determination of organic carbon in soil. Com Soil Plant Anal 19: 1467–1476

    Google Scholar 

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Kumar, V., Gilkes, R.J. & Bolland, M.D.A. The agronomic effectiveness of reactive rock phosphate, partially acidulated rock phosphate and monocalcium phosphate in soils of different pH. Fertilizer Research 34, 161–171 (1993). https://doi.org/10.1007/BF00750111

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