Conclusions
From results obtained in an investigation of modulation effects in the electron spin echo of adducts of VO2+acac2 with nitrogen-containing donor bases, we have been able to determine the constants of HFI of the unpaired electron of the vanadium with the nitrogen nucleus, for a large class of these bases. The values of the HFI constant are in the range 3.6–6 MHz.
The sensitivity of modulation effects in ESE to the selection of the base offers a means for determining the relative stability of these adducts.
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Translated from Zhurnal Strukturnoi Khimii, Vol. 26, No. 3, pp. 53–58, May–June, 1985.
Translated from Zhurnal Strukturnoi Khimii, Vol. 26, No. 3, pp. 53–58, May–June, 1985.
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Astashkin, A.V., Dikanov, S.A. & Tsvetkov, Y.D. Coordination of vanadyl acetylacetonate with nitrogen-containing donor bases. J Struct Chem 26, 363–368 (1985). https://doi.org/10.1007/BF00749372
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DOI: https://doi.org/10.1007/BF00749372