Conclusions
Isotope dilution together with deep cooling, as was shown above, provides a convenient method for refining the parameters of H vibrations, including their anharmonicity. The complicated spectra into which the “simple” H bands of ordinary tert-butanol are converted upon cooling, of course, contain information on the structure of the crystal which has not yet been interpreted in addition to the information already disclosed above. These spectra, as usual, are radically simplified by isotope dilution. On the other hand, the trivial Davydov doublet of chain crystals of alcohols is paradoxically complicated by isotope dilution, “crystal” effects, which are not understood, being displayed.
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Scientific-Research and Planning Institute of the Nitrogen Industry and Products of Organic Synthesis. Translated from Zhurnal Strukturnoi Khimii, Vol. 30, No. 1, pp. 92–99, January–February, 1989.
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Iogansen, A.V., Rozenberg, M.S. Infrared bands of the OH (OD) group, hydrogen bonding, and special features of the structure of crystals of tert-butanol at 15–350 K. J Struct Chem 30, 76–83 (1989). https://doi.org/10.1007/BF00748186
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DOI: https://doi.org/10.1007/BF00748186