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Journal of Structural Chemistry

, Volume 34, Issue 1, pp 46–55 | Cite as

Construction of vibrational basis spectra of multicomponent systems 1. Aerosil

  • I. V. Markichev
  • I. natkanets
  • E. F. Sheka
Article
  • 24 Downloads

Abstract

Aerosil (pyrogenous dispersed silica) is considered as a three-component system consisting of a silica core, hydroxyl shell, and adsorbed water. Factoring was carried out for its amplitude-weighted vibrational state density (AWSD) spectra obtained using inelastic neutron scattering at 10 K into the spectra of the components comprising this system. The factoring method used is based on the postulate of lack of correlation of the basis spectra. The factoring was carried out by the construction of physically significant basis spectra satisfying the zero linear correlation coefficient criterion for a set of AWSD spectra of the starting and modified samples of Aerosil A380.

Keywords

Physical Chemistry Hydroxyl Inorganic Chemistry Linear Correlation Adsorbed Water 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1993

Authors and Affiliations

  • I. V. Markichev
  • I. natkanets
  • E. F. Sheka

There are no affiliations available

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