Summary
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1.
Equations are derived for the influence of fluctuations on dielectric constant and loss in individual liquids and solutions in the region of dispersion of electromagnetic waves.
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2.
Equations are derived for the relationship between mean local and macroscopic or effective values of ε′ and ε″.
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3.
Measurements of ε′ and ε′ in acetone-benzene solutions at λ=3.21 cm and 8.15 mm, performed over wide ranges of concentration and temperature, are in quantitative agreement with theory.
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Literature cited
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J. H. Calderwood and C. P. Smyth, J. Am. Chem. Soc.78, 5, 1295 (1956).
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Translated from Zhurnal Strukturnoi Khimii, Vol. 2, No. 1, pp. 13–19. January-February, 1961
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Kasimov, R.M., Shakhparonov, M.I. & Akhadov, Y.Y. Influence of fluctuations on the dielectric properties of solutions in super-high frequency electromagnetic fields. J Struct Chem 2, 9–14 (1961). https://doi.org/10.1007/BF00744849
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DOI: https://doi.org/10.1007/BF00744849