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Model for chemical reaction kinetics in perchloric acid-ammonia flames

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Combustion, Explosion and Shock Waves Aims and scope

Abstract

We continue the study begun in [1, 2] of chemical processes in perchloric acid—ammonia flames. We propose new channels for the reaction. Based on experimental data on the chemical structure of an ammonium perchlorate flame and flames in O2/NH3/Ar, NH3/HClO4/H2O/Ar mixtures, we estimate the rate constants for steps that have not been well studied and refine the kinetic mechanism of [1, 2]. We discuss calculation results for the chemical structure of a flame in an NH3/HClO4/H2O/Ar mixture and an ammonium perchlorate flame. We simplify the kinetic mechanism.

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Authors
  1. N. E. Ermolin
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Additional information

Institute of Theoretical and Applied Mechanics, Siberian Branch, Russian Academy of Sciences, Novosibirsk 630090. Translated from Fizika Goreniya i Vzryva, Vol. 31, No. 5, pp. 58–69, September–October, 1995.

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Ermolin, N.E. Model for chemical reaction kinetics in perchloric acid-ammonia flames. Combust Explos Shock Waves 31, 555–565 (1995). https://doi.org/10.1007/BF00743807

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  • DOI: https://doi.org/10.1007/BF00743807

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