Abstract
The structure of salts formed from nitroform and a number of 4-amino-l, 2, 4-triazole bases has been investigated. It was found that some of the salts contain two molecules of triazole base and one of nitroform. From IR spectra it is inferred that the salts contain the nitroform anion, and a proton bound to one of two triazole rings, the amino groups not participating in salt-formation. Formation of 2∶1 salts of nitrogen bases is observed for the first time.
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References
E. H. White, J. Am. Chem. Soc., 77, 6215, 1955.
N. Albert and R. M. Badger, J. Chem. Phys., 29, 1193, 1958.
D. Cook, Can. J. Chem., 11, 2794, 1963.
D. Cook, Chem. Ind. (London), 607, 1963.
D. Hadzi, J. Chem. Soc., 5128, 1962.
M. Szafran, Bull. Acad. Polon, Sci., Ser. Sci. Chim., 11, 111, 169, 497, 503, 1963.
M. Szafran, Bull. Acad. Polon. Sci., Ser. Sci. Chim., 12, 289, 1964.
E. Schmidt, Ber., 52, 400, 1919.
W. Otting, Ber., 89, 2887, 1956.
B. Witkop, J. Patrick, and H. Hussman, Ber., 85, 949, 1952.
B. Chenon and C. Sandorty, Can. J. Chem., 36, 1181, 1958.
J. Bellanto, Spectrochim. acta, 16, 1344, 1960.
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Slovetskii, V.I., Brusnikina, V.M., Khmel'nitskii, L.I. et al. Special features of the structure of some salts of triazole bases. Chem Heterocycl Compd 2, 330–333 (1967). https://doi.org/10.1007/BF00742381
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DOI: https://doi.org/10.1007/BF00742381