Abstract
Basicity constants for a number of 1, 2, 4-triazole derivatives are determined. An assumed amine structure for 3-amino-1, 2, 4-triazoles in aqueous solution is demonstrated. It is assumed that protonization of 3- and 4-amino-1, 2, 4-triazoles occurs at the nitrogen in the heterocyclic ring, and not at the amino group.
Similar content being viewed by others
References
K. T. Potts, Chem. Rev., 31, 87, 1961.
G. Dedichen, Ber., 39, 1849, 1906.
S. T. Angyal and C. L. Angyal, J. Chem. Soc., 1461, 1952.
G. I. Chipen, V. Ya. Grinshtein, and M. B. Til'tin'sh, Izv. AN LatvSSR, ser. khim., 3, 393, 1962.
J. Mathieu and A. Allais, Principles of Organic Synthesis [Russian translation], IL, Moscow, 591, 1962.
T. Curtius and A. Darapsky, Ber., 40, 836, 1907.
R. A. Henry and W. G. Finnegan, J. Am. Chem. Soc., 76, 290, 1954.
M. R. Atkinson and G. W. Polya, J. Chem. Soc., 141, 1954.
C. Ainsworth and R. Jones, J. Am. Chem. Soc., 77, 621, 1955.
Syn. Org. Prep [in Russian], 4, 48, 1953.
I. Thiele and K. Heidenreich, Ber., 26, 2598, 1893.
V. Ya. Grinshtein and G. I. Chipen, ZhOKh, 31, 886, 1961.
G. I. Chipen and V. Ya. Grinshtein, Izv. AN LatvSSR, ser. khim., 2, 263, 1962.
Syn. Org. Prep [in Russian], 3, 56, 1952.
R. Herbst and J. Garrison, J. Org. Chem., 18, 872, 1953.
S. S. Novikov, Z. Ya. Lapshina, and V. A. Rudenko, Izv. AN SSSR, OKhN, 1902, 1960.
R. N. Strewe and R. K. Charlesworth, U.S. Patent no. 2744116; C. A., 51, 489, 1957.
H. S. Simms, J. Am. Chem. Soc., 48, 1239, 1925.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Bagal, L.I., Pevzner, M.S. & Lopyrev, V.A. Basicity and structure of 1, 2, 4-triazole derivatives. Chem Heterocycl Compd 2, 323–325 (1967). https://doi.org/10.1007/BF00742379
Issue Date:
DOI: https://doi.org/10.1007/BF00742379