Abstract
Studies are made of the IR spectra of 2-furylorganylsilanes, 2-furylorganylhydrosilanes,β-(2-furyl)ethylsilanes, 2-furfurylamino-, 2-furfuryloxy-, and 2-furfurylmercaptosilanes, organosilicon esters and amides of furan carboxylic acids, and 2, 5-disubstituted furylorganosilanes, and of Raman spectra ofβ-(2-furyl)ethylsilanes. Absorption band frequencies of furan ring bonds in furan organosilicon derivatives are discussed. Inductive constants and effective electronegativities of 2-furyl and 5-methyl-2-furyl groups are calculated from the experimental values ofν Si-H for 2-furylorganylhydrosilanes and 5-methyl-2-furyl-organylhydrosilanes, showing that the -I effects of the two groups are considerably greater than that of the phenyl group.
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For Part XII see [1].
We are greatly indebted to A. Grinvald and S. Aleksandrov for determining the spectra.
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Lukevits, E.Y., Voronkov, M.G. Furan organosilicon compounds. Chem Heterocycl Compd 2, 238–244 (1967). https://doi.org/10.1007/BF00742355
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DOI: https://doi.org/10.1007/BF00742355