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Morphology of corrosion products formed on cobalt and nickel in argon-oxygen-chlorine mixtures at 1000 K

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Abstract

The morphology of corrosion products formed on cobalt and nickel in argonoxygen-chlorine mixtures at 1000 K have been examined using optical microscopy, scanning electron microscopy, and X-ray diffraction. The corrosion products formed under conditions where the oxides are thermodynamically stable consist of porous oxides containing little or no chlorine. This morphology is consistent with a corrosion mechanism involving vapor phase transport of volatile metal chlorides.

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McNallan, M.J., Liang, W.W., Oh, J.M. et al. Morphology of corrosion products formed on cobalt and nickel in argon-oxygen-chlorine mixtures at 1000 K. Oxid Met 17, 371–389 (1982). https://doi.org/10.1007/BF00742118

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