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Mass-spectrometric investigation of the petroleum sulfides in the 170–310°c fraction of Arlansk petroleum

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Chemistry and Technology of Fuels and Oils Aims and scope

Summary

  1. 1.

    A mass spectrometric study was made of the group composition of petroleum sulfides, separated by selective extraction from the 170–310° distillate of Arlansk petroleum using aqueous sulfuric acid solutions.

  2. 2.

    The thiophene content of the separated sulfides did not exceed 3.8 mole %.

  3. 3.

    Petroleum sulfide fractions consist mainly of alkyl thiocyclanes, with smaller amounts of alkyl thiobi- and thiotricyclanes (15–30 and 4–14 mole%, respectively).

  4. 4.

    The thioalkane and alkyl cycloalkyl sulfide contents are low (0–13 and 0–20 mole %. respectively).

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Literature cited

  1. Ya. B. Chertkov, V. G. Spirkin, and V. N. Demishev, Inventor's Certificate USSR 197063, Byull. izobr., No. 12 (1967).

  2. G. D. Gal'pern, G. P. Girina, and V. G. Luk'yanitsa, in Methods of Analysis of Organic Compounds of Petroleum, Their Mixtures and Derivatives [in Russian], Izd. AN SSSR (1965), p. 58.

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Authors and Affiliations

  1. All-Union Scientific-Research Institute for Oil and Gas Processing and Production of Synthetic Liquid Fuel, USSR

    R. A. Khmel'nitskii, E. S. Brodskii, Ya. B. Chertkov & V. G. Spirkin

Authors
  1. R. A. Khmel'nitskii
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  2. E. S. Brodskii
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  3. Ya. B. Chertkov
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  4. V. G. Spirkin
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Additional information

Translated from Khimiya i Tekhnologia Topliv i Massel, No. 1, pp. 55–57, January, 1970.

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Khmel'nitskii, R.A., Brodskii, E.S., Chertkov, Y.B. et al. Mass-spectrometric investigation of the petroleum sulfides in the 170–310°c fraction of Arlansk petroleum. Chem Technol Fuels Oils 6, 65–67 (1970). https://doi.org/10.1007/BF00729744

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  • DOI: https://doi.org/10.1007/BF00729744

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