Journal of Superconductivity

, Volume 9, Issue 6, pp 615–618 | Cite as

A structural study of chemical stability of (Y1−xCax)(Ba2−xLa x )Cu3O7−δ(x= 0.0, 0.2, and 0.4)

  • H. Rajagopal
  • A. Sequeira
  • R. Ganguly
  • J. V. Yakhmi
Article

Abstract

Neutron structural studies are made on (Y1−xCax)(Ba2−xLa x )Cu3O7−δ for compositions corresponding to x=0.0, 0.2, and 0.4 in order to evaluate any correlation between the remarkably high chemical stability of the cosubstituted samples (x=0.2 and 0.4) and the structural parameters. It is suggested that the increased chemical stability is caused by a decrease in the puckering of the Cu-O planes with increase inx, causing them to flatten, which leads to a reduction in the internal stresses existing in the perovskite lattice of this technologically important material.

Key words

Y-123 structure chemical stability internal stress puckering of Cu-O planes neutron structure 

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Copyright information

© Plenum Publishing Corporation 1996

Authors and Affiliations

  • H. Rajagopal
    • 1
  • A. Sequeira
    • 1
  • R. Ganguly
    • 2
  • J. V. Yakhmi
    • 2
  1. 1.Solid State Physics DivisionBhabha Atomic Research CentreMumbai (Bombay)India
  2. 2.Chemistry DivisionBhabha Atomic Research CentreMumbai (Bombay)India

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