Abstract
A cadmium analogue of the mercury system with nominal composition CdBa2(Ca1−xYx)Cu2Oy has been synthesized. Thex=0 samples contain about 12 vol.% of the 1212 phase but are not superconducting. Thex=0.3 samples are superconducting atT on = 103 K. The EDX analysis of 18 microcrystals shows a broad cationic distribution of the different components. The observed broad superconducting transition is attributed to the variousT c of the different microcrystals.
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S. N. Putilin, E. V. Antipov, O. Chmaissem, and M. Marezio,Nature (London)362, 226 (1993).
A. Schilling, M. Cantoni, J. D. Guo, and R. Ott,Nature (London)363, 56 (1993).
R. L. Meng, L. Beauvais, X. N. Zhang, Z. J. Huang, Y. Y. Sun, Y. Y. Xue, and C. W. Chu,Physica C 216, 21 (1993).
K. Remschnig, P. Rogl, R. Eibler, G. Hilscher, N. Pillmayr, H. Kirchmayr, and E. Bauer,Physica C 153–155, 906 (1988).
M. T. Andreas and A. I. Kingon,Chem. Mater. 3, 428 (1991).
T. P. Beales, C. Dineen, W. G. Freeman, S. R. Hall, M. R. Harrison, D. M. Jacobson, and S. J. Zammattio,Supercond. Sci. Technol. 5, 47 (1992).
Qian Yitai, Tang Kaibin, Yang Peidong, Chen Zuyao, Li Rukang, Zhou Guien, and Zhang Yuheng,Physica C 209, 516 (1993).
A. Maignan, G. Van Tendeloo, M. Hervieu, C. Michel, and B. Raveau,Physica C 212, 239 (1993).
D. Pelloquin, M. Hervieu, C. Michel, G. Van Tendeloo, A. Maignan, and B. Raveau,Physica C 216, 257 (1993).
S. H. H. Naqvi and I. W. Boyd,Physica C 213, 161 (1993).
A. Maignan, C. Michel, G. Van Tendeloo, M. Hervieu, and B. RaveauPhysica C 216, 1 (1993).
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Balchev, N., Lovchinov, V., Gattef, E. et al. Superconductivity at 103 K in CdBa2(Ca0.7Y0.3)Cu2O y . J Supercond 8, 329–331 (1995). https://doi.org/10.1007/BF00728166
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DOI: https://doi.org/10.1007/BF00728166