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Chemistry and Technology of Fuels and Oils

, Volume 2, Issue 2, pp 92–95 | Cite as

Sulfonation of residual oils and utilization of the oil sulfonation product

  • V. I. Antonishin
  • B. S. Grinenko
Petroleum and Gas Processing
  • 37 Downloads

Summary

Reactions of sulfonation, sulfone formation, oxidation, and condensation take place during the action of sulfuric acid or oleum on oil. In the oxidation of the oils, burning off of side-chain alkyl and cycloalkyl substituents takes place, with formation of carboxyl groups and phenolic hydroxyl groups in the structure of the sulfonation product, and with liberation of carbon dioxide and water of reaction, as well as oxidiative dehydrogenation of naphthenic rings to aromatic ones and oxidative condensation of oil sulfonation products.

The oil sulfonation product possesses ion exchange properties and may be used as an ion exchange material.

Keywords

Dioxide Hydroxyl Carbon Dioxide Carboxyl Sulfuric Acid 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    V. I. Antonishin and B. S. Grinenko, Sulfonation of asphaltenes, Neft' i Gaz, No. 5 (1965).Google Scholar
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    V. I. Antonishin and B. S. Grinenko, Sulfonation of petroleum resins, Scientific-Technological Collection: Petroleum Refining and Petroleum Chemistry, No. 10 (1965).Google Scholar
  3. 3.
    B. M. Rybak, Analysis of Petroleum and Petroleum Products. State Fuel Technology Press (1962).Google Scholar
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    Methods of Investigation of Petroleum and Petroleum Products. State Fuel Technology Press (1955).Google Scholar
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    C. B. Kincannon and T. E. Wier, Anal. Chem.,22, 864 (1950).Google Scholar

Copyright information

© Consultants Bureau 1967

Authors and Affiliations

  • V. I. Antonishin
    • 1
  • B. S. Grinenko
    • 1
  1. 1.L'vov Polytechnic InstituteUSSR

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