Skip to main content
SpringerLink
Log in

Role of solid acceptors in the oxidative dehydrogenation of hydrocarbons with iodine

  • Petroleum and Gas Processing
  • Published:
Chemistry and Technology of Fuels and Oils Aims and scope

Conclusions

  1. 1.

    It is shown that at small iodine feeds the dehydrogenation indices both for isopentane and for n-butane are significantly inferior, in the reactor filled with solid acceptor, to the corresponding indices in the reactor filled with the quartz filler alone or the reactor filled with a combination of quartz filler and acceptor.

  2. 2.

    The iodination indices for the iodinated acceptor and the quartz filler are identical.

  3. 3.

    It is established that the role of the solid acceptor consists only in the absorption of HI with the formation of an iodide which is not oxidized during the time of the reaction cycle.

  4. 4.

    The oxidation of the iodide to iodine takes place only during the acceptor regeneration cycle when the raw material is not being fed to the reactor.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. V. A. Kolobikhin, V. M., Sobolev, D. A. Bol'shakov, and M. I. Myasoedov, Neftekhimiya,4, No. 4, 535 (1964).

    Google Scholar 

  2. V. A. Kolobikhin, M. I. Myasoedov, and V. M. Sobolev, Khim. Prom., No. 9 (1965).

  3. V. A. Kolobikhin, G. A. Stepanov, M. I. Myasoedov, and R. V. Chugunnikova, Neftekhimiya,5, No. 6, 815 (1965).

    Google Scholar 

  4. S. V. Adel'son and M. M. Nikonova, Monomers and Intermediate Products of Petrochemical Synthesis [in Russian], Izd. Khimiya (1967), p. 9.

  5. S. V. Adel'son, M. M. Nikonova, and V. I. Nikonov, Khim. i Tekhnol. Topliv i Masel, No. 2 (1967).

  6. I. Ya. Tyuryaev, S. B. Grinenko, I. L. Kadilova, Yu. I. Kozorezov, and V. V. Zhuponenko, Neftekhimiya,6, No. 1, 71–75 (1966).

    Google Scholar 

  7. Dutch Patent No. 106343, October 15, 1963.

  8. British Patent No. 985500, May 2, 1962; C. A.,59, No. 10, 11243 (1963).

  9. British Patent No. 983907, November 17, 1965; C. A.,63, 490 (1965).

  10. V. A. Kolobikhin, G. A. Stepanov, and R. V. Chugunnikova, Khim. Prom., No. 4 (1966).

  11. N. N. Semenov, Certain Problems in Chemical Kinetics and Reactivity [in Russian], Izd. AN SSSR (1958).

Download references

Author information

Authors and Affiliations

  1. Academician I. M. Gubkin Moscow Institute of the Petrochemical and Gas Industry, USSR

    S. V. Adel'son & M. M. Nikonova

Authors
  1. S. V. Adel'son
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. M. Nikonova
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Khimiya i Tekhnologiya Topliv i Masel., No. 6, pp. 8–11, June, 1969.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Adel'son, S.V., Nikonova, M.M. Role of solid acceptors in the oxidative dehydrogenation of hydrocarbons with iodine. Chem Technol Fuels Oils 5, 395–399 (1969). https://doi.org/10.1007/BF00722483

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00722483

Keywords

Search

Navigation