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Destruction of vanadium metalloporphyrin complexes in the action of γ radiation on petroleum or petroleum products

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Chemistry and Technology of Fuels and Oils Aims and scope

Summary

  1. 1.

    The possibility of decomposing the vanadium-porphyrin complex by the action ofγ radiation on eastern petroleum or Bakinsk diesel fuel has been demonstrated.

  2. 2.

    The extent of decomposition of the vanadium-porphyrin complex as a function of radiation dose has been established. The optimum dose of radiation for eastern petroleum is 108 to 109 rads; and for Bakinsk diesel fuel it is 104 rads.

  3. 3.

    With increase in radiation dose the quantity of free radicals decreases.

  4. 4.

    The quantity of unsaturated compounds in Bakinsk diesel fuel increased with an increase in radiation dose, but the fractional composition did not change significantly.

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Literature cited

  1. L. S. Polak, Proceedings of the 2nd All-Union Conference on Radiation Chemistry, Press of the AN SSSR, [in Russian] (1962), p. 282.

  2. A. M. Brodskii, K. P. Lavronskii, and V. B. Titov, Ibid. [in Russian] (1962), p. 295.

  3. A. V. Topchiev, I. V. Vereshchinskii, P. Ya. Glazunov, V. E. Glushnev, and L. S. Polak, et al., Ibid. [in Russian], (1962), p. 304.

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  8. E. A. Glebovskaya and M. V. Vol'kenshtein, Spectra of Porphyrins in Petroleums and Asphalts, Zhurn. Obshch. Khimii [in Russian], No. 8 (1948).

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Authors and Affiliations

  1. Institute of Chemistry of Petroleum and Natural Salts, Academy of Sciences of the KazSSR, USSR

    A. V. Kotova, V. G. Ben'kovskii, V. B. Bulgakov & N. Kh. Valisheva

Authors
  1. A. V. Kotova
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  2. V. G. Ben'kovskii
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  3. V. B. Bulgakov
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  4. N. Kh. Valisheva
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Additional information

Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 8, pp. 22–24, August, 1966.

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Kotova, A.V., Ben'kovskii, V.G., Bulgakov, V.B. et al. Destruction of vanadium metalloporphyrin complexes in the action of γ radiation on petroleum or petroleum products. Chem Technol Fuels Oils 2, 539–541 (1966). https://doi.org/10.1007/BF00719206

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  • DOI: https://doi.org/10.1007/BF00719206

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