Polymer Bulletin

, Volume 22, Issue 5–6, pp 483–488 | Cite as

Polymerization of acrylamide initiated by the redox system Ce(IV)-4,4′-azobis (4-cyano pentanol)

  • Ümit Tunca
  • I. Ersin Serhatli
  • Yusuf Yağci
Article

Summary

Acrylamide was polymerized by eeric ion Ce (IV)-4,4′-azobis(4-cyano pentanol)(ACP) redox pair in aqueous nitric acid under nitrogen atmosphere. The rate of polymerization is proportional to [M]2,[ACP] and [Ce(IV)]−1. Termination mechanism which was exclusively linear offered one azo group per polymeric chain. The obtained polyacrylamide can be used as a water soluble initiator for vinyl polymerization.

Keywords

Nitrogen Polymerization Atmosphere Polyacrylamide Nitric Acid 

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Copyright information

© Springer-Verlag 1989

Authors and Affiliations

  • Ümit Tunca
    • 1
  • I. Ersin Serhatli
    • 1
  • Yusuf Yağci
    • 1
  1. 1.Department of ChemistryIstanbul Technical UniversityIstanbulTurkey

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