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Determination of zinc and lead in additives and additive oils

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Chemistry and Technology of Fuels and Oils Aims and scope

Summary

A rapid method has been developed for determining zinc and lead in additives and additive oils, based on an ion-exchange chromatographic separation of the elements on the polymer Anionit ÉDÉ-10 P, with subsequent complexometric titration of the solutions using xylenol orange indicator.

The method gives good repeatability of results from the lead and zinc determinations; the deviations between parallel determinations are at most 2% (rel.) when the metal content of the sample is above 0.5%. Good reproducibility was obtained when comparing the proposed method with standard gravimetric and ASTM methods. The time required to determine zinc and lead when both are present along with barium, phosphorus, and sulfur is not more than 5–6 h.

The proposed method is recommended for use in scientific research institutes and in plant laboratories.

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Literature cited

  1. K. M. Salldadze, Ion Exchange Resins [in Russian], Izd. AN SSSR, scientific-popular series (1959).

  2. M. N. Svereva, Zab. labor.,24, No. 4 (1958).

  3. A. T. Kabakov, Zav. labor.,26, No. 12 (1960).

  4. R. Kunin and R. J. Myers, Ion Exchange Resins [Russian translation], IL (1960).

  5. A. Schwartz and J. Perry, Berg J. Surfactants and Detergents [Russian translation], IL (1960).

  6. A. K. Babko and I. V. Pyatnitskii, Quantitative Analysis [in Russian], Izd. “Vysshaya shkola” (1962).

  7. Petroleum Products, Method of Determining Ash Content [in Russian],GOST 1461-59 [All-Union State Standard].

  8. Bertolachchini, Determination of Barium, Calcium, and Zinc in Additive Oils [in Russian], GOSINTI (1958).

  9. ASTM Standards on Petroleum products and lubricants, 38th Edition, October (1961).

  10. R. Belcher, A. M. G. McDonald, Talanta, 1, No. 4 (1958), pp. 408–410.

    Google Scholar 

  11. V. G. Sochevanov, N. V. Shmakova, A. T. Martynov, and G. A. Volkova, Zav. labor.,26, No. 4 (1960).

  12. Determination of Phosphorus in Additives and Additive Oils [in Russian], GOST 9827-61 [All-Union State Standard].

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Authors and Affiliations

  1. All-Union Scientific Research Institute for Petroleum and Gas Processing and Synthetic Liquid Fuel Production, USSR

    N. P. Sosnina, A. I. Tarasov & V. P. Muzychenko

Authors
  1. N. P. Sosnina
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  2. A. I. Tarasov
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  3. V. P. Muzychenko
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Sosnina, N.P., Tarasov, A.I. & Muzychenko, V.P. Determination of zinc and lead in additives and additive oils. Chem Technol Fuels Oils 1, 404–407 (1965). https://doi.org/10.1007/BF00718566

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  • DOI: https://doi.org/10.1007/BF00718566

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