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The acceleration of wax oxidation by adding Mn-K salts of aliphatic acids

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Chemistry and Technology of Fuels and Oils Aims and scope

Summary

  1. 1.

    It has been shown that the rate of wax oxidation in the presence of an equimolecular mixture of manganese and potassium acetates is close to that observed when potassium permanganate or Mn-K soaps are used. The acids produced are characterized by low ester values.

  2. 2.

    A method has been developed for preparing a Mn-K (Na) catalyst based on the salts from low molecular weight acids and manganese carbonate or its ores. The activity of the catalyst is somewhat lower than that of an equimolecular mixture of manganese and potassium acetates.

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Literature cited

  1. B. N. Tyutyunnikov and A. A. Perchenko, Khim. i tekhnol. topliv i masel, No. 4 (1960).

  2. B. V. Erofeev, A. I. Chirko, and L. N. Sorokina, Uchenye zapisi BGU im. Vi. I. Lenina, seriya khimicheskaya, No. 20 (1954).

  3. B. V. Erofeev, and A. I. Chirko, Uchenye zapisi BGU im. V. I. Lenin, seriya khimicheskaya, No. 20 (1954).

  4. A. A. Perchenko, Mas-zhir. prom., No. 2 (1959).

  5. V. M. Gol'dberg, L. K. Obukhova, and N. M. Emanuel', Neftekhimiya, 2 (1962), p. 229.

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  6. B. N. Tyutyunnikov and A. A. Perchenko, Authors' certificate 145,221, June 22, 1961, Byul. No. 5 (1962).

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Authors and Affiliations

  1. Kharkov Polytechnic Institute, USSR

    B. N. Tyutyunnikov & A. A. Perchenko

  2. All-Union Scientific Research Institute for Synthetic and Natural Fats, USSR

    B. N. Tyutyunnikov & A. A. Perchenko

Authors
  1. B. N. Tyutyunnikov
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  2. A. A. Perchenko
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Additional information

In the experimental portion of the work, we were assisted by P. A. Luk'yanenko and Z. P. Selina.

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Tyutyunnikov, B.N., Perchenko, A.A. The acceleration of wax oxidation by adding Mn-K salts of aliphatic acids. Chem Technol Fuels Oils 1, 366–369 (1965). https://doi.org/10.1007/BF00718555

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  • DOI: https://doi.org/10.1007/BF00718555

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