Skip to main content
SpringerLink
Log in

Composition and structure of solid petroleum hydrocarbons which form urea complexes

  • Published:
Chemistry and Technology of Fuels and Oils Aims and scope

Conclusions

Analysis of the chemical composition of the solid petroleum hydrocarbons which form urea complexes shows that they compose a group of hydrocarbons of varied chemical structure (normal alkanes and isoalkanes, alkylcyclanes and alkylarenes) which have as a mandatory structural element a long unbranched alkyl chain. The chemical composition of solid hydrocarbon fractions isolated from petroleum with urea depends on the nature of the petroleum and the character of the feedstock fraction (low-boiling or high-boiling distillates or residues from distillation).

A feature of the molecular structure of the solid saturated petroleum hydrocarbons which form urea complexes — the presence of a long unbranched alkyl chain in conjunction with general low branchedness of isoalkane or alkylcyclane molecules—determines the commonness of various properties and phase behavior of the fractions being studied, which makes this group of hydrocarbons close in many ways to normal alkanes. The principles given present interest in consideration of distillate paraffins composed predominantly of complex-forming hydrocarbons.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. F. Kramer, Inclusion Compounds [Russian translation], IL (1958).

  2. A. I. Kitaigorodskii, Organic Crystallochemistry [in Russian], Izd. AN SSSR (1955).

  3. O. Redlich, G. M. Gable, A. K. Dunlop, and E. J. Miller, J. Am. Chem. Soc.,72, No. 9 (1950).

  4. W. Lommerzheim, Erdöl u. Kohle,7, No. 4 (1954).

  5. G. Heinze, Erdöl u. Kohle,7, No. 4 (1954).

  6. R. W. Schiessler and D. J. Feitter, J. Am. Chem. Soc.,74, No. 7 (1952).

  7. W. Fuchs and J. Neus, Erdöl u. Kohle,7, No. 3 (1954).

  8. W. Fuchs, Transactions of the IVth International Petroleum Congress [in Russian], Vol. 6, Gostoptekhizdat (1956), p. 185.

  9. S. R. Sergienko and E. V. Lebedev, Izv. Akad. Nauk TurkmSSR, No. 5 (1959).

  10. E. F. Yatsenko and N. I. Chernozhukov, Khim. i Tekhnol. Topliv i Masel, No. 3 (1960).

  11. A. V. Topchiev, L. M. Rozenberg, L. M. Terent'eva, and N. A. Nechitailo, in: Composition and Properties of the High-Molecular Part of Petroleum [In Russian], Izd. AN SSSR (1958), p. 208.

  12. P. I. Sanin and N. K. Druzhinina, Neftekhimiya, No. 6 (1961).

  13. A. A. Mikhnovskaya, M. I. Krasavchenko, L. Z. Osityanskaya, and A. A. Petrov, in: Geochemistry of Organic Fuel Accumulations and Their Deposits [in Russian], Izd. AN SSSR (1962), p. 36.

  14. A. A. Mikhnovskaya, M. I. Krasavchenko, L. Z. Osityanskaya, and A. A. Petrov, in: Medium and Processes of Petroleum Formation [in Russian], Izd. “Nauka” (1964), p. 61.

  15. M. J. O'Neal, in: Applied Mass-spectrometry [Russian translation], Gostoptekhizdat (1958), p. 36.

  16. R. J. Clerc, A. Hood, and M. J. O'Neal, J. Anal. Chem.,27, No. 6 (1955).

  17. M. J. O'Neal, A. Hood, R. J. Clerc, M. L. Ander, and S. K. Hines, Transactions of IVth Internation Petroleum Congress [in Russian], Vol. 6, Gostoptekhizdat (1956), p. 298.

  18. N. I. Chernozhukov and L. P. Kazakova, Neft. Khoz., No. 8 (1956).

  19. N. I. Chernozhukov and L. P. Kazakova, Khim. i Tekhnol. Topliva, No. 1 (1956).

  20. N. I. Chernozhukov and L. P. Kazakova, Khim. i Tekhnol. Topliv i Masel, No. 1 (1957).

  21. N. I. Chernozhukov and L. P. Kazakova, Coll., Materials of Interuniversity Conference on Questions of New Technique in the Petroleum Industry [in Russian], Vol. 2 (1958), p. 146.

    Google Scholar 

  22. N. I. Chernozhukov and L. P. Kazakova, Coll., Composition and Properties of the High-Molecular Part of Pe- troleum [in Russian], Izd. AN SSSR (1958), p. 203.

  23. N. I. Chernozhukov, S. É. Krein, and B. V. Losikov, The Chemistry of Mineral Oils [in Russian], Gostoptekhizdat (1959), p. 46.

  24. V. A. Bogdanova, Izv. VUZ, Neft' i Gaz, No. 9 (1958).

  25. K. S. Lipovskaya and E. V. Voznesenskaya, Khim. i Tekhnol. Topliv i Masel, No. 4 (1962); No. 12 (1962).

  26. L. G. Zherdeva, E. N. Sorokina, and O. A. Slabkovskaya, Khim. i Tekhnol. Topliv i Masel, No. 3 (1965).

  27. S. R. Sergienko and E. V. Lebedev, Selective Catalytic Dehydrogenation of High-Molecular Hydrocarbons [in Russian], Izd. AN TurkmSSR (1961).

  28. R. L. MacLaughlin, in: The chemistry of Petroleum Hydrocarbons [Russian translation], Vol. 1, Gostoptekhizdat (1958), p. 202.

  29. S. Midzusima, The structure of Molecules and Internal Rotation [Russian translation], IL (1957).

  30. S. S. Kurtz, in: The Chemistry of Petroleum Hydrocarbons [Russian translation], Vol. 1, Gostoptekhizdat (1958), p. 227.

  31. S. W. Ferris, W. H. Harwey, and J. F. Ritter, as cited in H. Bennet, Industrial Waxes, Vol. 1, New York (1963), p. 16.

  32. A. N. Guseva and I. E. Leifman, Khim. i Tekhnol. Topliv i Masel, No. 10 (1966).

  33. A. A. Schaerer, C. J. Busso, A. E. Smith, and L. B. Skinner, J. Am. Chem. Soc.,77, No. 7 (1955).

  34. G. Constantinides and S. Valussi, Riv. Combustibili,8, No. 7–8 (1954).

  35. A. N. Guseva, L. D. Ashkinadze, and I. E. Leifman, Neftekhimiya, No. 5 (1962).

  36. A. N. Guseva, I. E. Leifman, and L. D. Ashkinadze, Izv. VUZ, Neft' i Gaz, No. 4 (1963).

  37. F. J. Ludwig, Anal. Chem.,37, No. 13 (1965).

  38. A. N. Guseva and I. E. Leifman, Khim. i Tekhnol. Topliv i Masel, No. 9 (1967).

  39. K. V. Gopalan, Transactions of IVth International Petroleum Congress [in Russian], Vol. 6, Gostoptekhizdat (1956), p. 330.

  40. A. A. Schaerer, G. C. Bayle, and W. M. Mazee, Rec. Trav. Chim.,75, No. 5 (1956).

  41. N. A. Nechitailo and G. B. Ravich, Uspekhi Khimii,26, No. 6 640 (1957).

    Google Scholar 

  42. Yu. V. Mnyukh, Zh. Strukt. Khim.,1, No. 3 (1960).

  43. N. A. Nechitailo, A. V. Topchiev, L. M. Rozenberg, and E. M. Terent'eva, Zh. Fiz. Khim.,34, No. 12 (1960).

  44. A. N. Guseva and I. E. Leifman, Coll., Solid Petroleum Hydrocarbons (Study, Preparation and Use) [in Russian], TsNIITÉneftekhim (1966), p. 7.

  45. A. N. Guseva and I. E. Leifman, Izv. VUZ, Neft' i Gaz, No. 8 (1966).

  46. K. Negoro, Bull. Chem. Soc. Japan,35, Nos. 6 and 3 (1962).

  47. B. A. Anurov, Yu. M. Korolev, and G. N. Nosov, “News of petroleum and gas technique,” Geologiya, No. 6 (1962).

Download references

Authors
  1. A. N. Guseva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. E. Leifman
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 7, pp. 22–25, July, 1968.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Guseva, A.N., Leifman, I.E. Composition and structure of solid petroleum hydrocarbons which form urea complexes. Chem Technol Fuels Oils 4, 499–503 (1968). https://doi.org/10.1007/BF00718050

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00718050

Keywords

Search

Navigation