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Degree of esterification of pentaerythritol esters of carboxylic acids in relation to thermal-oxidative stability

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Chemistry and Technology of Fuels and Oils Aims and scope

Conclusions

  1. 1.

    The stability of PEE depends on the degree of esterification; with increasing concentration of unesterified hydroxyl groups, the stability of the ester decreases.

  2. 2.

    The oxidation of PEE by oxygen at 200°C is accompanied by thermal-oxidative breakdown with the formation of alcohols and acids.

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Literature cited

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  2. V. S. Kiselev, Handbook for Practical Work in Technology of Film-Forming Materials [in Russian], Goskhimizdat, Moscow (1948), p. 58.

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  4. L. J. Bellamy, The Infrared Spectra of Complex Molecules, Methuen, London (1954).

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Authors
  1. L. L. Kalinin
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  2. G. T. Novosartov
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  3. V. K. Krashenninikova
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  4. I. A. Kuz'michenkova
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Additional information

Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 1, pp. 22–24, January, 1975.

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Kalinin, L.L., Novosartov, G.T., Krashenninikova, V.K. et al. Degree of esterification of pentaerythritol esters of carboxylic acids in relation to thermal-oxidative stability. Chem Technol Fuels Oils 11, 28–30 (1975). https://doi.org/10.1007/BF00717307

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  • DOI: https://doi.org/10.1007/BF00717307

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