Chemistry and Technology of Fuels and Oils

, Volume 9, Issue 3, pp 192–196 | Cite as

Effect of hydrocarbon composition of wax on quality of synthetic fatty acids

  • A. A. Perchenko
  • M. A. Marchenko
Article
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Summary

  1. 1.

    A study has been made of the effect of raw-material composition on the yield and composition of acids, in the example of oxidation of petroleum paraffin waxes containing 91.2 and 73.4% n-alkanes.

    The yield of technical mixed water-insoluble acids, based on the wax processed, is 82.3 and 84.2% by weight, respectively. The respective yields of C5−C20 distilled acids with respect to the technical mixed acids are 68.3 and 64% by weight, and with respect to the 100% acids are 63 and 57.2%.

     
  2. 2.

    The C10−C16 and C17−C20 acids obtained by oxidation of waxes containing 91.2 and 73.4% alkanes contain (respectively) unsaponifiables 0.5 and 2.3, 1.0 and 4%; iso-acids, 8.3 and 5.2, 14.2 and 8.9%; dibasic acids, 2.2 and 4.1, 3.6 and 5.5%; total amount of impurities, including unsaturated acids and keto-acids, 19.2 and 25.1, 28 and 35.4%.

     

Keywords

Oxidation Petroleum Hydrocarbon Alkane Paraffin 

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Literature cited

  1. 1.
    P. G. Igonin, V. S. Dorodnova, A. V. Romanov, and M. Ya. Mal'tsev, Khim. i Tekhnol. Topliv i Masel, No. 6, 26 (1962).Google Scholar
  2. 2.
    N. K. Man'kovskaya, Synthetic Fatty Acids [in Russian], Khimiya, Moscow (1965), p. 17.Google Scholar
  3. 3.
    A. A. Perchenko, M. A. Marchenko, P. N. Uzunkoyan, V. K. Ievlev, and R. N. Korobeinik, Khim. i Tekhnol. Topliv i Masel, No. 6, 28 (1967).Google Scholar
  4. 4.
    A. A. Perchenko, G. A. Goryacheva, and A. V. Oberemko, Neftepererab. i Neftekhim. (Izd. TsNIITÉneftekhim), No. 1, 34 (1970).Google Scholar
  5. 5.
    A. A. Perchenko and M. A. Marchenko, Khim. i Tekhnol. Topliv i Masel, No. 4, 30 (1970).Google Scholar
  6. 6.
    A. A. Perchenko, A. I. Il'ina, and M. A. Marchenko, Khim. Prom., No. 4, 14 (1971).Google Scholar

Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • A. A. Perchenko
    • 1
  • M. A. Marchenko
    • 1
  1. 1.VNISINZhUSSR

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