Summary
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1.
The calculation of retention indices by means of additive schemes gives results that are insufficiently accurate for reliable identification of isomers.
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2.
Relationships have been proposed that will provide data on the retention of C8–C9 isoparaffins with an accuracy on the order of 1–2 index units, and that of C10 hydrocarbons with an accuracy on the order of 5 index units.
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Literature cited
A. T. James and A. J. P. Martin, Biochem. J.,50, 679 (1952).
E. Harrington, in: Advances in Gas Chromatography [Russian translation], Gostoptekhizdat (1961), p. 67.
A. J. P. Martin, Biochem. Soc. Symposia, Vol. 3, Cambridge (1950), p. 4; Ann. Rev. Biochem.,19, 517 (1950).
V. G. Berezkin, Neftekhim.,1 (1961);2 (1962).
M. B. Evans and J. F. Smith, J. Chromatog.,5, 300 (1961);8, 303 (1962).
M. S. Vigdergauz, in: Gas Chromatography [in Russian], Trudy VNIGNI, No. 64, Izd. Nedra (1970), p. 82.
V. G. Berezkin, G. L. Gromova, O. E. Grinkina, and S. S. Yarovoi, Neftekhim.,10 (1970).
S. W. Benson and J. H. Buss, J. Chem. Phys.,29, 546 (1958); Chem. Rev.69, 279 (1969).
V. M. Tatevskii, Chemical Structure of Hydrocarbons and Correlation of Physicochemical Properties [in Russian], Izd. MGU (1963).
K. Altenburg, Kolloid-Z.,178, 112 (1961);189, 144 (1963); Z. Physik. Chem. (Leipzig),228, 120 (1965);230, 13 (1965);231, 77 (1966);234, 136 (1967).
. A. Martinov and M. S. Vigdergauz, Neftekhim.,10, (1970).
E. Kovăts, Helv. Chim. Acta,41, 1915 (1958).
D. A. Tourres, J. Chromatog.,30, No. 2, 357 (1967).
A. Matukuta, Seventh International Symposium on Gas Chromatography, Paper No. 4, Copenhagen (1968).
J. J. Walraven, A. W. Ladan, and A. I. M. Keulemans, Chromatog.,1, 195 (1968).
A. W. C. Van Kemenade and H. Groenendijk, Chromatog.,2, 316 (1969).
K. Altenburg, Gas Chromatography in 1968 [in German], Vortaege des Y Symposiums Über Gas-Chromatographie, Akad. Verlag., Berlin (1968), p. 1.
N. L. Allinger and M. J. Nakazaki, J. Am. Chem. Soc.,81, 4074 (1959).
V. M. Sakharov, S. A. Leont'eva, and N. I. Lulova, Neftekhim.,10 (1970).
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Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 10, pp. 55–58, October, 1972.
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Vigdergauz, M.S., Martynov, A.A., Lezina, S.K. et al. Identification of isomeric paraffinic hydrocarbons by calculations from chromatographic data. Chem Technol Fuels Oils 8, 796–800 (1972). https://doi.org/10.1007/BF00717081
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DOI: https://doi.org/10.1007/BF00717081