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Use of gas chromatography to identify components of decomposition products from “sul'fol” antiscuff additive

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Chemistry and Technology of Fuels and Oils Aims and scope

Summary

  1. 1.

    Gas chromatography has been used to identify the thermal decomposition products (boiling below 318°C) from the antiscuff additive Sul'fol, using (a) retention indices, both literature and calculated values; (b) differences in retention index on weakly polar (E-301) and strongly polar (PEG-1500) phases; (c) literature and experimental values of relative retention volumes; (d) calculated boiling points of components; and (e) differences in detector signals based on thermal conductivity and hydrogen flame.

  2. 2.

    It has been found that the main products from the thermal decomposition of the additive Sul'fol are 1-chloropropyne-1 and other chlorinated hydrocarbons, as well as unsaturated hydrocarbons with 8, 10, 11, and 12 carbon atoms.

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Authors and Affiliations

  1. All-Union Scientific-Research Institute for Petroleum Processing, USSR

    N. A. Kudryavtseva, A. A. Fatalieva, N. I. Lulova & I. É. Vinogradova

Authors
  1. N. A. Kudryavtseva
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  2. A. A. Fatalieva
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  3. N. I. Lulova
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  4. I. É. Vinogradova
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Additional information

Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 10, pp. 47–51, October, 1972.

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Kudryavtseva, N.A., Fatalieva, A.A., Lulova, N.I. et al. Use of gas chromatography to identify components of decomposition products from “sul'fol” antiscuff additive. Chem Technol Fuels Oils 8, 786–790 (1972). https://doi.org/10.1007/BF00717079

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  • DOI: https://doi.org/10.1007/BF00717079

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