Skip to main content
SpringerLink
Log in

Polar and protective properties of esters

  • Published:
Chemistry and Technology of Fuels and Oils Aims and scope

Summary

  1. 1.

    A number of esters used as aviation oils and hydraulic fluids have been investigated with respect to polar and electron donor-acceptor properties at an interface with metal. It has been shown that the majority of the esters are high in dielectric permeability and that they decrease the electron work function of metals, being electron donors and being sorbed at the > CO = group.

  2. 2.

    The least polar of the esters is the pentaerythritol ester of C5–C9 acids, which increases the electron work function. The sorption of esters on metal is in the nature of a physical adsorption. Satisfactory protective properties and the capability for rapid removal of an electrolyte from a metal surface are provided by the esters of mmethylcyclohexanol, adipic acid, and 2-ethylhexanol (No. 7), the monodecyl ester of diphenic acid (No. 8), and the didecyl ester of benzylsuccinic acid (No. 9).

  3. 3.

    Esters can be utilized as components of combination corrosion inhibitors, but all of the esters that were investigated are inferior in this respect to fatty acids.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. A. Altsibeeva and S. Levin, Inhibitors of Metallic Corrosion [in Russian], Izd. Khimiya (1968).

  2. J. Bregman, Corrosion Inhibitors [Russian translation], Izd, Khimiya (1968).

  3. S. É. Krein, P. I. Sanin, et al. (editors), Oil and Fuel Additives [in Russian], Gostoptekhizdat (1961).

  4. S. É. Krein and P. I. Sanin, et al. (editors), Oil and Fuel Additives [in Russian], Vol. 1, Izd. Khimiya (1966).

  5. S. A. Balezin, A. G. Voskresenskii, and É. G. Zak, Inhibitors of Metallic Corrosion [in Russian], Izd. Sudostroenie (1965).

  6. S.A. Balezin and A. G. Voskresenskii, Uch. Zap. Mosk. Gos. Ped. Inst., No. 303, Collection No. 3, pp. 295–298 (1969).

    Google Scholar 

  7. I. L. Rozenfel'd et al., Zh. Prikl. Khim.,34, No. 9 (1961).

  8. R. E. Hatton, Hydraulic Fluids [Russian translation], V. V. Vainshtok (editor), Izd. Khimiya (1965).

  9. A. I. Dintses and A. V. Druzhinina, Synthetic Lubricating Oils [in Russian], Gostoptekhizdat (1958).

  10. R. S. Gunderson and A. V. Hart (editors), Synthetic Lubricants and Fluids [Russian translation], Izd. Khimiya (1965).

  11. Petroleum Oils and Additives, Tr. VNII NP, No. 12, Div. IV, Izd. Khimiya (1970), pp. 320–333.

  12. V. N. Minkin, O. A. Osipov, and Yu. A. Zhdanov, Dipole Moments in Organic Chemistry [in Russian], Izd. Khimiya (1968).

  13. A. A. Markov, G. I. Kichkin, et al., Khim. i Tekhnol. Topliv i Masel, No. 10 (1970).

  14. L. N. Teterina, G. G. Kotorova, et al., Khim. i Tekhnol. Topliv i Masel, No. 11 (1970).

  15. Yu. N. Shekhter, I. G. Fuks, et al., Khim. i Tekhnol. Topliv i Masel, No. 8 (1969).

  16. S. É. Krein, Yu. N. Shekhter, et al., Zashchita Metallov,5, No. 6 (1969).

  17. S. É. Krein, Yu. N. Shekhter, et al., Zashchita Metallov,5, No. 6 (1969).

  18. Inhibitors, Preservative Lubricants, and Preservation of Metal Articles [in Russian], Vols. 1 and 2, TsNIIT-Éneftekhim (1969).

  19. L. N. Teterina, Yu. N. Shekhter, et al., Neftepererab. i Neftekhim., No. 11 (1969).

  20. T. I. Ambartsumyan, É. A. Smiotanko, et al., Khim. i Tekhnol. Topliv i Masel, No. 7 (1970).

  21. É. A. Smiotanko, Yu. N. Shekhter, et al., Neftepererab. i Neftekhim., No. 2 (1970).

  22. Yu. N. Shekhter, Metal Corrosion Protection [in Russian] (1964).

  23. S. Fuji and K. Aramaki, Proceedings of Third World Congress on Metal Corrosion [Russian translation], Vol. 2, Izd. Mir (1966).

  24. B. N. Sazhin et al., Electrical Properties of Polymers [in Russian], Izd. Khimiya (1970).

  25. G. Mathe and A. Alley, Principles of Organic Synthesis [Russian translation], IL (1962).

  26. Yu. N. Shekhter, N. G. Fuks, et al., Khim. i Tekhnol. Topliv i Masel, No. 12 (1970).

  27. S. É. Krein and Yu. N. Shekhter, Nitrated Oils [in Russian], Izd. Khimiya (1967).

  28. A. L. Dol'berg, Yu. N. Shekhter, and L. D. Khoroshilova, Avtomob. Prom., No. 8 (1970).

  29. Yu. N. Shekhter, E. V. Fertman, et al., Khim. i Tekhnol. Topliv i Masel, No. 1 (1969); S. É. Krein, N. D. Blagovidov, et al., Khim. i Tekhnol. Topliv i Masel, No. 5 (1970).

Download references

Author information

Authors and Affiliations

  1. Moscow Pilot Plant of All-Union Scientific-Research Institute for Petroleum Processing, USSR

    K. M. Antipova, Yu. N. Shekhter, V. M. Nikonorov, E. V. Ivanova, L. Kh. Kagan, I. G. Fuks & E. V. Fertman

  2. I. M. Gubkin MoscowInstitute of the Petrochemical and Gas Industry, USSR

    K. M. Antipova, Yu. N. Shekhter, V. M. Nikonorov, E. V. Ivanova, L. Kh. Kagan, I. G. Fuks & E. V. Fertman

Authors
  1. K. M. Antipova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. N. Shekhter
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. M. Nikonorov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. V. Ivanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. L. Kh. Kagan
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. I. G. Fuks
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. E. V. Fertman
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 10, pp. 43–46, October, 1972.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Antipova, K.M., Shekhter, Y.N., Nikonorov, V.M. et al. Polar and protective properties of esters. Chem Technol Fuels Oils 8, 781–785 (1972). https://doi.org/10.1007/BF00717078

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00717078

Keywords

Search

Navigation