Conclusions
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1.
The kinetics were studied of the hydropurification process of thermocracking kerosenes on an alumo-cobalt-molybdenum catalyst.
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2.
It was shown that the apparent rate constants of the hydrogenation reaction of unsaturateds and the desulfurization reaction are approximately equal and that the rate constant of hydrocracking is lower by two orders. The apparent activation energy of hydrocracking is highest.
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3.
It was confirmed that on an alumo-cobalt-molybdenum catalyst the hydrogenation and hydrogenolysis reaction evidently occurs in the volume.
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4.
It was revealed that under conditions of hydropurification at a pressure of 40 atm and specific circulation of hydrogen-containing gas of 1000 liters/(liter · h), external-diffusion inhibition of the process occurs.
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Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 12, pp. 1–4, December, 1971.
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Smol'nik, Y.E., Zhurba, A.S., Katrush, R.V. et al. Kinetics of the hydrogenation process of thermocracking kerosenes. Chem Technol Fuels Oils 7, 885–888 (1971). https://doi.org/10.1007/BF00716578
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DOI: https://doi.org/10.1007/BF00716578