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Zeolite guest-host interactions: Implications in formation, catalysis, and photochemistry

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Abstract

This review primarily focuses on contributions of our research group in the area of zeolite guesthost chemistry. The perturbation of the Raman spectra of the organic structure-directing-agents during synthesis of zeolites ZK-4, ZSM-5, and ferrierite show clearly the entrapment of the organic by the aluminosilicate framework. The microordering around the organic coincides with the development of longrange-order typical of crystal formation. Using three examples involving zeolite entrapped organometallic complexes of manganese(III), cobalt(II), and ruthenium(II), we have demonstrated a wide range of chemistries using reactants varying from olefins to dioxygen to photogenerated electrons.

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  1. Prabir K. Dutta
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Dutta, P.K. Zeolite guest-host interactions: Implications in formation, catalysis, and photochemistry. J Incl Phenom Macrocycl Chem 21, 215–237 (1995). https://doi.org/10.1007/BF00709417

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