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Coordination chemistry in zeolites

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Abstract

Researchers have devised several procedures for synthesizing transition metal ion (TMI) complexes in zeolite cavities and channels. Two main routes have been envisaged: synthesis with a preformed complex and complex assembly in the zeolite. An overview of the different preparation methods and of the TMI-complexes, encaged in zeolites, is given. These complexes have been mainly studied in zeolite Y. The zeolite is a non-coordinating anion, a solvent, or a ligand. It reduces the mobility of the complexes and provides chemisorption sites. Future developments will comprise the use of widepore zeolites and zeotypes (e.g., VPI-5, MCM-41, hexagonal faujasite) and the design of optically active surfaces. Furthermore, there is a need for quantification in general and for selectively synthesizing one type of complex.

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Authors
  1. Dirk E. De Vos
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  2. Peter. P. Knops-Gerrits
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  3. Rudy F. Parton
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  4. Bert M. Weckhuysen
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  5. Peter A. Jacobs
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  6. Robert A. Schoonheydt
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De Vos, D.E., Knops-Gerrits, P.P., Parton, R.F. et al. Coordination chemistry in zeolites. J Incl Phenom Macrocycl Chem 21, 185–213 (1995). https://doi.org/10.1007/BF00709416

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