Abstract
The various strategies for the preparation of zeolite ship-in-a-bottle complexes are reviewed. Key examples of the cluster, flexible ligand, template and zeolite synthesis methods are described. Evidence for the intrazeolite location of the metal complexes as well as the prevailing interpretation of these results have been organized in terms of the various methods of characterization. A brief summary of known reactivity studies of zeolite encapsulated metal complexes, including catalytic oxidations and hydrogenations, is also presented.
Similar content being viewed by others
References
N. Herron, G. D. Stucky, and C. A. Tolman,Inorg. Chim. Acta,100, 135 (1985).
N. Herron,Inorg. Chem.,25, 4714 (1986).
N. Herron, C. A. Tolman, and G. D. Stucky,J. Chem. Soc., Chem. Commun., 1521 (1986).
R. Parton, D. De Vos, and P. A. Jacobs, inProceedings of the NATO Advanced Study Institute on Zeolite Microporous Solids: Synthesis, Structure and Reactivity, E. G. Derouane, F. Lemos, C. Naccache, and F. R. Ribeiro (Eds), Kluwer, Dordrecht, pp 555–578 (1992).
N. Herron,Chemtech,19, 542 (1989).
V. Yu. Zakharov and B. V. Romanovsky,Vestn. Mosk. Univ., Ser. Khim.,18, 142 (1977) [Eng. Trans. inSov. Mosc. Univ. Bull.,32, 16 (1977)].
B. V. Romanovsky, R. E. Mardaleishvili, V. Yu. Zakharov, and O. M. Zakharova,Vestn. Mosk. Univ., Ser. 2: Khim.,18, 232 (1977).
V. Yu. Zakharov and B. V. Romanovsky,Vestn. Mosk. Univ., Ser. 2: Khim.,18, 348 (1977).
V. Yu. Zakharov, O. M. Zakharova, B. V. Romanovsky, and R. E. Mardaleishvili,React. Kinet. Catal. Lett.,6, 133 (1977).
M. V. Gusenkov, V. Yu. Zakharov, and B. V. Romanovsky,Neftekhimiya,18, 105 (1978).
O. M. Zakharova and B. V. Romanovsky,Vestn. Mosk. Univ., Ser. 2: Khim.,20, 284 (1979).
B. V. Romanovsky, O. M. Zakharova, and V. Yu. Zakharov,Vestn. Mosk. Univ., Ser. 2: Khim.,20, 43 (1979).
V. Yu. Zakharov and B. V. Romanovsky,Vestn. Mosk. Univ., Ser. 2: Khim.,20, 78 (1979).
S. V. Gudkov, E. S. Shpiro, and B. V. Romanovsky,Izv. Akad. Nauk. SSSR, Ser. Khim., 2448 (1980).
S. V. Gudkov, B. V. Romanovsky, E. S. Shpiro, G. V. Antoshin, and Kh. M. Minachev,VINITI Deposited Doc., 2472 (1980), [CA95:61069n (1981)].
O. M. Zakharova and B. V. Romanovsky,Neftekhimiya,21, 924 (1981).
B. V. Romanovsky, inProceedings of the 8th International Congress on Catalysis, Verlag Chemie, Weinheim, p 657 (1984).
G. Meyer, D. Wohrle, D. Mohl, and G. Schultz-Ekloff,Zeolites,4, 30 (1984).
A. N. Zakhatov and B. V. Romanovsky,J. Inclus. Phenom.,3, 389 (1985).
N. Herron, G. D. Stucky, and C. A. Tolman,J. Chem. Soc., Chem. Commun., 1521, (1986).
T. V. Korol'kova and B. V. Romanovsky,Neftekhimiya,26, 546 (1986).
N. Herron,J. Coord. Chem.,19, 25 (1988).
Y. W. Chan and R. B. Wislon,Preprint Papers-ACS, Div. Fuel Chem.,33, 453 (1988).
T. Kimura, A. Fukuoka, and M. Ichikawa,Shokubai,31, 357 (1988).
T. Kimura, A. Fukuoka, and M. Ichikawa,62th CATSJ Meeting Abstr.: No. 1D203,30, 444 (1988).
T. Kimura, A. Fukuoka, and M. Ichikawa,64th CATSJ Meeting Abstr.: No. 1A09,31, 357 (1989).
M. Ichikawa, T. Kimura, and A. Fukuoka,Stud. Surf. Sci. Catal.,60, 335 (1991).
T. Kimura, A. Fukuoka, and M. Ichikawa,Catal. Lett.,4, 279 (1990).
K. J. Balkus, Jr. and J. P. Ferraris,J. Phys. Chem.,94, 8019 (1990).
J. P. Ferraris, K. J. Balkus, Jr., and A. Schade,J. Inclus. Phenom. Molec. Recog. Chem.,14, 163 (1992).
K. J. Balkus, Jr., A. A. Welch, and B. E. Gnade,J. Inclus. Phenom. Molec. Recog. Chem. 10, 141 (1991).
Z. Jiang and Z. Xi,Fenzi Cuihua,6, 467 (1992), [CA,118: 212554 (1992)].
W. Zhang, X. Ye, and Y. Wu,Fenzi Cuihua,5, 168 (1991), [CA115: 143584x (1991)]
A. N. Zakharov,Mendeleev Commun., 80 (1991).
H. Diegruber, P. J. Plath, and G. Schultz-Ekloff,J. Mol. Catal.,24, 115 (1984).
E. S. Shpiro, G. V. Antoshin, O. P. Tkachenko, S. V. Gudkov, B. V. Romanovsky, and Kh. M. Minachev,Stud. Surf. Sci. Catal.,18, 31 (1984).
A. G. Gabrielov, A. N., Zakharov, B. V. Romanovsky, O. P. Tkachenko, E. S. Shpiro, and Kh. M. Minachev,Koord. Khim.,14, 821 (1988).
A. G. Gabrielov, A. N. Zakharov, and B. V. Romanovsky,Koord. Khim.,14, 214 (1988).
M. Tanaka, Y. Sakai, T. Tominaga, A. Fukuoka, T. Kimura, and M. Ichikawa,J. Radioanal. Nucl. Chem., Lett.,137, 287 (1989).
M. Tanaka, Y. Minai, T. Watanabe, and T. Tominaga,J. Radioanal. Nucl. Chem., Lett.,154, 197 (1991).
M. Tanaka, Y. Minai, T. Watanabe, and T. Tominaga,J. Radioanal. Nucl. Chem., Lett.,164, 255 (1992).
A. N. Zakharov, B. V. Romanovsky, D. Luka, and V. I. Sokolov,Organomet. Chem. USSR,1, 64 (1988).
A. N. Zakharov, A. G. Gabrielov, B. V. Romanovsky, and V. I. Sokolov,Vestn. Mosk. Univ., Ser. 2: Khim.,30, 234 (1989).
G. Schultz-Ekloff, D. Wohrle, and A. Andreev,Wiss. Zeitschr. Leuna-Merseburg,32, 649 (1990).
R. F. Parton, L. Utytterhoeven, and P. A. Jacobs,Stud. Surf. Sci. Catal.,59, 395 (1991).
R. F. Parton, D. R. C. Huybrechts, Ph. Buskens, and P. A. Jacobs,Stud. Surf. Sci. Catal.,70, 47 (1991).
B. V. Romanovsky and A. G. Gabrielov,Mendeleev Commun., 14 (1991).
B. V. Romanovsky and A. G. Gabrielov,Stud. Surf. Sci. Catal.,72, 443 (1992).
B. V. Romanovsky and A. G. Gabrielov,J. Mol. Catal.,74, 293 (1992).
F. Bedioui, E. DeBoysson, J. Devynck, and K. J. Balkus, Jr.,J. Electroanal. Chem., Interfac. Electrochem.,315, 313 (1991).
R. Parton, Dissertation, Katholieke Universiteit Leuven (1993).
E. Paez-Mozo, N. Gabriunas, F. Lucaccioni, D. D. Acosta, P. Patrono, A. La Ginestra, P. Ruiz, and B. Delmon,J. Phys. Chem.,97, 12819 (1993).
M. Nakamura, T. Tatsumi, and H. Tominaga,Bull. Chem. Soc. Jpn.,63, 3334 (1990).
X. Wang, Y. Liang, Y. Lui, L. Yu, Y. Li, F. Li, and X. Cao,Gaodeng Xuexiao Hiaxue Xuebao,14, 19 (1993) [CA119: 107854j (1993)].
C. Bowers and P. K. Dutta,J. Catal.,122, 271 (1990).
K. J. Balkus, Jr., A. A. Welch, and B. E. Gnade,Zeolites,10, 722 (1990).
S. Kowalak, R. C. Weiss, and K. J. Balkus, Jr.,J. Chem. Soc., Chem. Commun., 57 (1991).
D. E. DeVos and P. A. Jacobs, inProceedings from the 9th International Zeolite Conference, R. Von Ballmoos, J. B. Higgins, and M. M. J. Treacy (Eds), Butterworth-Heinemann, Boston, Vol. 2, pp 615–622 (1992).
K. Putyera, G. Plesch, L. Benco, J. Dobrovodsky, A. V. Tchuvaev, V. I. Nefedov, and M. Zikmund,Proc. 12th Conf. Coord. Chem., 295 (1990).
F. Bedioui, E. DeBoysson, J. Devynck, and K. J. Balkus, Jr.,J. Chem. Soc., Farad. Trans.,87, 3831 (1991).
L. Gaillon, N. Sajot, F. Bedioui, J. Devynck, and K. J. Balkus, Jr.,J. Electroanal. Chem., Interfac. Electrochem.,345, 157 (1993).
F. Bedioui, L. Roue, L. Gaillon, J. Devynck, S. L. Bell, and K. J. Balkus, Jr.,Petrol. Preprints,38, 529 (1993).
K. J. Balkus, Jr., and S. Shepelev,Micropor. Mater.,1, 383 (1993).
K. J. Balkus, Jr., and S. Shepelev,Petrol. Preprints,38, 512 (1993).
G. A. Ozin and C. Gil,Chem. Rev.,89, 1749 (1989).
N. Jaeger, P. Plath, and G. Schultz-Ekloff,Acta Phys. Chem.,31, 189 (1985).
W. M. H. Sachtler,Acc. Chem. Res.,26, 383 (1993).
P. Gallezot, inMetal Clusters, E. M. Moskovits (Ed.), J. Wiley, New York, pp 219–247 (1986).
G. A. Ozin, S. Ozkar, and R. A. Prokopowicz,Acc. Chem. Res.,25, 553 (1992).
W. M. Meier and D. H. Olson,Atlas of Zeolite Structure Types, Butterworth-Heinemann, Boston (1992).
M. Ichikawa,Adv. Catal.,38, 283 (1992).
L. F. Rao, A. Fukuoka, and M. Ichikawa,J. Chem. Soc., Chem. Commun., 458 (1988).
L. F. Rao, A. Fukuoka, N. Kosugi, H. Kuroda, and M. Ichikawa,J. Phys. Chem.,94, 5317 (1990).
N. Takahashi, A. Mijin, H. Suematsu, S. Shinohara, and H. Matsuoka,J. Catal.,177, 348 (1989).
B. E. Hanson, M. E. Davis, D. Taylor, and E. Rode,Inorg. Chem.,23, 52 (1984).
P. Gelin, C. Naccache, and Y. Ben Taarit,Pure Appl. Chem.,60, 1315 (1988).
M. Ichikawa, L.-F. Rao, and A. Fukuoka,Catal. Sci. Tech.,1, 111 (1991).
A. Fukuoka, L.-F. Rao, N. Kosugi, H. Kuroda, and M. Ichikawa,Appl. Catal.,50, 295 (1989).
L. L. Sheu, H. Knozinger, and W. M. H. Sachtler,Catal. Lett.,2, 129 (1989).
L. L. Sheu, H. Knozinger, and W. M. H. Sachtler,J. Am. Chem. Soc.,111, 8125 (1989).
R. S. Drago, I. Bresinska, J. E. George, K. J. Balkus, Jr., and R. J. Taylor,J. Am. Chem. Soc. 110, 304 (1988).
R. J. Taylor, R. S. Drago, and J. E. George,J. Am. Chem. Soc.,111, 6610 (1989).
R. J. Taylor, R. S. Drago, and J. P. Hage,Inorg. Chem.,31, 253 (1992).
I. Bresinska and R. S. Drago,Stud. Surf. Sci. Catal.,69, 101 (1991).
M. Iwamoto, S.-I. Nakamura, H. Kusano, and Sh. Kagawa,J. Phys. Chem.,90, 5244 (1986).
P.-L. Zhou and B. C. Gates,J. Chem. Soc., Chem. Commun., 347 (1989).
P.-L. Zhou, S. D. Maloney, and B. C. Gates,J. Catal.,129, 315 (1991).
S. Kawi and B. C. Gates,J. Chem. Soc., Chem. Commun., 702 (1992).
S. Kawi, J.-R. Chang, and B. C. Gates,J. Catal.,142, 585 (1993).
R. Nakamura, N. Okada, A. Oomura, and E. EchigoyaChem. Lett.,119 (1984).
A. De Mallmann and D. Barthomeuf,Catal. Lett.,5, 293 (1990).
G. J. Li, T. Fujimoto, A. Fukuoka, and M. Ichikawa,J. Chem. Soc., Chem. Commun., 1337 (1991).
G. J. Li, T. Fujimoto, A. Fukuoka, and M. Ichikawa,Catal. Lett.,12, 171 (1992)
G. J. Li, M. Ichikawa, T. Fujimoto, and X. Guo,Petrol. Preprints,30, 523 (1993).
S. Kawi, J.-R. Chang, and B. C. Gates,Catal. Lett.,10, 263 (1991).
S. Kawi, J.-R. Chang, and B. C. Gates,J. Phys. Chem.,97, 10599 (1993).
T. Bein, S. J. McLain, D. R. Corbin, R. D. Farlee, K. Moller, G. D. Stucky G. Woolery, and S. Sayers,J. Am. Chem. Soc.,110, 1801 (1988).
S. Kawi and B. C. Gates,J. Chem. Soc., Chem. Commun., 994 (1991).
C. Bremard, E. Denneulin, C. Depecker, and P. Legrand,Stud. Surf. Sci. Catal.,48 219 (1989).
A. G. Gabrielov, K. J. Balkus, Jr., F. Bedioui, and J. Devynck,Micropor. Mater.,2, 119 (1994).
K. J. Balkus, Jr., A. G. Gabrielov, F. Bedioui, and J. Devynck,Inorg. Chem.,33, 67 (1994).
V. J. Frilette and R. W. Maatman,U. S. Patent 3,373,109 (1968).
C. A. Rundell and C. V. McDaniel,U. S. Patent 3,769,386 (1973).
L. A. Rankel and E.W. Valyocsik,U. S. Patent 4,500,503 (1985).
L. A. Rankel and E.W. Valyocsik,U. S. Patent 4,388,285 (1983).
F. Delprato, L. Demotte, J. L. Guth, and L. Huve,Zeolites,10, 564 (1990
K. J. Balkus, Jr. and S. Kowalak,U. S. Patent 5,167,942 (1992).
K. J. Balkus, Jr., C. D. Hargis, and S. Kowalak,ACS Symp. Ser.,499, 347 (1992).
K. J. Balkus, Jr., S. Kowalak, K. T. Ly, and C. D. Hargis,Stud. Surf. Sci. Catal.,69, 93 (1991).
R. Hoppe, G. Schultz-Ekloff, D. Wöhrle, M. Ehrl, and C. Bräuchle,Stud. Surf. Sci. Catal.,69, 199 (1991).
S. Wohlrab, R. Hoppe, G. Schultz-Ekloff, and D. Wöhrle,Zeolites,12, 862 (1992).
E. W. Valyocsik,U. S. Patent 4,568,654 (1986).
K. J. Balkus, Jr. and S. Shepelev, Unpublished results.
K. J. Balkus, Jr., A. D. Sherry, and S. W. Young,U. S. Patent 5,122,363 (1992).
K. J. Balkus, Jr., I. Bresinska, and S. W. Young, inProceedings from the 9th International Zeolite Conference, R. Von Ballmoos, J. B. Higgins, and M. M. J. Treacy (Eds), Butterworth-Heinemann, Boston, Vol. 2, pp 193–201 (1992).
D. R. Rolisson,Chem. Rev.,90, 867 (1990).
A. J. Bard, and T. E. Mallouk, inMolecular Design of Electrode Surfaces, R. W. Murray (Ed), J. Wiley, New York, p 271 (1992).
F. Bedioui, L. Roue, E. Briot, J. Devynck, S. L. Bell, and K. J. Balkus, Jr.,J. Electroanal. Chem., Interfac. Electrochem. in press.
M. G. B. Drew inSpectroscopic and Computational Studies of Supramolecular Species, J. E. D. Davies (Ed), Kluwer, Dordrecht, pp 207–237 (1992).
P. C. H. Mitchell,Chem. Ind. 308, (1991).
B. V. Romanovsky,Acta Phys. Chem.,31, 215 (1985).
B. V. Romanovsky, inHomogeneous and Heterogeneous Catalysis, I. Y. Ermakov and V. A. Likholobov (Eds), VNU Sci. Press, Utrecht, pp 343–365 (1986).
B. V. Romanovsky and A. G. Gabrielov,Neftekhimiya,30, 617 (1990).
C. A. Tolman and N. Herron,Catal. Today,3, 235 (1988).
N. Herron, inInclusions Compounds, J. L. Atwood, J. E. D. Davies, and D. D. MacNicol (Eds), Oxford University Press, Oxford, Vol. 5, pp 90–103 (1991).
D. R. C. Huybrechts, R. F. Parton, and P. A. Jacobs,Stud. Surf. Sci. Catal.,60, 225 (1991).
J. Weitkamp, inProceedings from the 9th International Zeolite Conference, R. Von Ballmoos, J. B. Higgins, and M. M. J. Treacy (Eds.), Butterworth-Heinemann, Boston, Vol. 2, pp 13–45 (1992).
G. Henrici-Olive and S. Olive,J. Mol. Catal.,1, 121 (1975–76).
R.-J. Wang, T. Fujimoto, T. Shido, and M. Ichikawa,J. Chem. Soc., Chem. Commun., 962 (1992).
J. S. Beck, J. C. Vartuli, W. Roth, M. E. Leonowicz, C. T. Kresge, K. D. Schmitt, C. T.-W. Chu, D. H. Olson, E. W. Sheppard, S. B. McCullen, J. B. Higgins, and J. L. Schlenker,J. Am. Chem. Soc.,114, 10834 (1992).
M. Estermann, L. B. McCusker, C. Baerlocher, A. Merrouche, and H. Kessler,Nature,352, 320 (1991).
Rights and permissions
About this article
Cite this article
Balkus, K.J., Gabrielov, A.G. Zeolite encapsulated metal complexes. J Incl Phenom Macrocycl Chem 21, 159–184 (1995). https://doi.org/10.1007/BF00709415
Issue Date:
DOI: https://doi.org/10.1007/BF00709415