Abstract
Several facets of pyridinocalixarene chemistry have been investigated including reaction pathways for their formation from the base-catalyzed alkylation of the parent calixarenes with PicCl·HCl, effect of the nature and identity of the base on regio- and stereoselectiveO-alkylations, creation of molecular asymmetry in calix[4]arenes and enantiomeric resolution, conformation and conformational mobility, and complexation.
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This paper is dedicated to the commemorative issue on the 50th anniversary of calixarenes.
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Bottino, F., Pappalardo, S. Synthesis and properties of pyridinocalixarenes. J Incl Phenom Macrocycl Chem 19, 85–100 (1994). https://doi.org/10.1007/BF00708976
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DOI: https://doi.org/10.1007/BF00708976