Abstract
A new series of tetrapyrazolic macrocycles with a functionalized sidearm has been prepared. Their capability to transport Li+ salts of carboxylic acids has been examined and is shown to be strongly dependent on the functionality of the macrocycle sidearm. In the case of the Li+ (D, L.)-mandelate, chiral recognition has been observed.
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Boudouche, S., Coquelet, C., Jacquet, L. et al. Chiral macrocycles, part I: Synthesis and enantioselective transport of carboxylic acids as their Li+ salts. J Incl Phenom Macrocycl Chem 16, 69–80 (1993). https://doi.org/10.1007/BF00708763
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DOI: https://doi.org/10.1007/BF00708763