Abstract
A series of synthetic ionophores containing two carboxylic acid groups were synthesized as carriers for alkaline earth metal cations. Among them, the lipophilic derivative having a trimenthylene bridge and multiple quinaldate moieties selectively transported barium ion from the basic aqueous phase to the acidic aqueous phase through the bulk dichloromethane liquid membrane. The cation selectivity was explained by considering the fit of the cation diameter with the pseudocyclic cavity.
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References
R. Hilgenfeld and W. Saenger:Top Curr. Chem. 101, 1 (1982).
G. R. Painter and B. C. Pressman:Top Curr. Chem. 101, 83 (1982).
J.-M. Lehn:Angew. Chem. Int. Ed. Engl. 27, 89 (1988).
M. Okahara and Y. Nakatsuji:Top. Curr. Chem. 128, 37 (1985).
Y. Nakatsuji and M. Okahara:Pure Appl. Chem. 63, 557 (1993).
K. Hiratani, H. Suigihara, K. Taguchi and K. Iio:Chem. Lett. 1657 (1983).
K. Taguchi, K. Hiratani, H. Suigihara and K. Iio:Chem. Lett. 1457 (1984).
T. M. Fyles, C. A. McGavin and D. M. Whitefield:J. Org. Chem. 49, 753 (1984).
W. Wierenga, B. R. Evans and J. A. Walterson:J. Am. Chem. Soc. 101, 1334 (1979).
S. Inokuma, T. Hayase and T. Kuwamura:J. Jpn. Oil Chem. Soc. (YUKAGAKU) 36, 340 (1987).
S. Inokuma, T. Hayase, S. Azechi and T. Kuwamura:J. Jpn. Oil Chem. Soc. (YUKAGAKU) 37, 28 (1988).
S. Inokuma, T. Hayase, S. Azechi and T. Kuwamura:J. Jpn. Oil Chem. Soc. (YUKAGAKU) 37, 287 (1988).
K. Yamaguchi, H. Kuboniwa, N. Murakami, A. Hirao, S. Nakahama and N. Yamazaki:Bull. Chem. Soc. Jpn. 62, 1097 (1989).
R. Wakita, M. Matsumoto, Y. Nakatsuji and M. Okahara:J. Membr. Sci. 57, 297 (1991).
Y. Nakatsuji, T. Inoue, M. Wada and M. Okahara:J. Incl. Phenom. 10, 379 (1991).
R. Wakita, M. Miyakoshi, Y. Nakatsuji, and M. Okahara:J. Incl. Phenom. 10, 127 (1991).
C. Moberg, M. Muhammed, G. Svensson and M. Weber:J. Chem. Soc., Chem. Commun. 810 (1988).
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Nakatsuji, Y., Matsumoto, M., Masuyama, A. et al. Synthetic noncyclic ionophores with multiple carboxylate groups for alkaline earth metal cations. J Incl Phenom Macrocycl Chem 18, 377–383 (1994). https://doi.org/10.1007/BF00707386
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DOI: https://doi.org/10.1007/BF00707386