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Variation of luminescence properties of the reaction solution during preparation of a component of Ziegler-Natta catalyst by the reaction of Tb with Ph3CCl

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Abstract

Photoluminescence is used to test lanthanide-C bonds and to identify unstable intermediates in the synthesis of Ph3CTbCl2, a component of Ziegler-Natta catalyst.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Academy of Sciences of the Republic of Bashkortostan, 141 prosp. Oktyabrya, 450071, Ufa, Russian Federation

    R. G. Bulgakov, G. G. Bikbaeva, R. G. Akhmadeev, S. P. Kuleshov, A. A. Gavrilova, G. L. Sharipov, Yu. G. Kuvatov, L. I. Sharapova, L. A. Safonova & T. A. Zypysheva

Authors
  1. R. G. Bulgakov
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  2. G. G. Bikbaeva
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  3. R. G. Akhmadeev
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  4. S. P. Kuleshov
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  5. A. A. Gavrilova
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  6. G. L. Sharipov
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  7. Yu. G. Kuvatov
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  8. L. I. Sharapova
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  9. L. A. Safonova
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  10. T. A. Zypysheva
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2053–2055, October, 1995.

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Bulgakov, R.G., Bikbaeva, G.G., Akhmadeev, R.G. et al. Variation of luminescence properties of the reaction solution during preparation of a component of Ziegler-Natta catalyst by the reaction of Tb with Ph3CCl. Russ Chem Bull 44, 1972–1973 (1995). https://doi.org/10.1007/BF00707243

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  • DOI: https://doi.org/10.1007/BF00707243

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