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Photochemical reduction of carbon dioxide to formate in the coordination sphere of MoH4(PH2PCH2CH2PPh2)2

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Abstract

UV, IR, and NMR spectra of photolysis products obtained by irradiation of MoH4(Ph2PCH2CH2PPh2)2 (1) in an atmosphere of CO2,13CO2, or C18O2 were studied. In the coordination sphere of1, photochemical reduction of carbon dioxide occurs, yielding products of formate type. Treatment of photoproducts with acids affords formaldehyde.

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Authors and Affiliations

  1. Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation

    A. P. Pivovarov

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  1. A. P. Pivovarov
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2043–2045, October, 1995.

The author is grateful to A. P. Borisov and V. D. Makhaev for providing a sample of MoH4(Ph2PCH2CH2PPh2)2.

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Pivovarov, A.P. Photochemical reduction of carbon dioxide to formate in the coordination sphere of MoH4(PH2PCH2CH2PPh2)2 . Russ Chem Bull 44, 1963–1965 (1995). https://doi.org/10.1007/BF00707238

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  • DOI: https://doi.org/10.1007/BF00707238

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