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Molecular structure of (diethyldithiocarbomoyl)diphenylthiophosphinate

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Abstract

X-Ray study of (diethyldithiocarbomoyl)diphenylthiophosphinate was carried out. AZ-conformation of the diethyldithiocarbomoyl ligand, which results in a short nonvalent intramolecular P...S contact (3.315 Å), is realized in the molecule. Steric hindrances in the molecule increase the P-S-C bond angle to 106.39°.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420083, Kazan', Russian Federation

    V. A. Al'fonsov, I. A. Litvinov, O. N. Kataeva, D. A. Pudovik & S. A. Katsyuba

Authors
  1. V. A. Al'fonsov
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  2. I. A. Litvinov
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  3. O. N. Kataeva
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  4. D. A. Pudovik
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  5. S. A. Katsyuba
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1978–1980, October, 1995.

The work was financially supported by the International Science Foundation (Gram RH1 000).

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Al'fonsov, V.A., Litvinov, I.A., Kataeva, O.N. et al. Molecular structure of (diethyldithiocarbomoyl)diphenylthiophosphinate. Russ Chem Bull 44, 1897–1899 (1995). https://doi.org/10.1007/BF00707222

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  • DOI: https://doi.org/10.1007/BF00707222

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