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Complexes of rhodium carbonylchloride and phosphorus(iii) cyanides in mediated electrochemical reduction of 2-carbomethoxy-2-methyl-1,1-dichlorocyclopropane

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Abstract

Electrochemical reduction of the complexes Rh(CO)ClL2 [L = (EtO)2PCN (1), Ph2PCN (2)] and Rh2(CO)4L [L = P(CN)3 (3),\(Ph\begin{array}{*{20}c} P \\ | \\ {CN} \\ \end{array} ---\begin{array}{*{20}c} P \\ | \\ {CN} \\ \end{array} Ph\) (4)] and their catalytic properties in electrochemical reduction of 2-carbomethoxy-2-methyl-1,1-dichloro-cyclopropane were studied. The catalytic electroreduction of a substrate at the reduction potentials of the central ion was developed for complexes2–4. This process is accelerated substantially for complexes2 and3 in the presence of anthracene.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420083, Kazan, Russian Federation

    V. V. Yanilkin, N. I. Maksimyuk, V. N. Nazmutdinova & L. P. Chirkova

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  1. V. V. Yanilkin
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  2. N. I. Maksimyuk
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  3. V. N. Nazmutdinova
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  4. L. P. Chirkova
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1970–1972, October, 1995.

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Yanilkin, V.V., Maksimyuk, N.I., Nazmutdinova, V.N. et al. Complexes of rhodium carbonylchloride and phosphorus(iii) cyanides in mediated electrochemical reduction of 2-carbomethoxy-2-methyl-1,1-dichlorocyclopropane. Russ Chem Bull 44, 1890–1891 (1995). https://doi.org/10.1007/BF00707219

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  • DOI: https://doi.org/10.1007/BF00707219

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