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On the structure of poly(2,4-dichlorophenylacetylene) from the data of resonance Raman spectra

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Abstract

The resonance Raman spectra of poly(2,4-dichlorophenylacetylene) in the range of wavelengths of the exciting radiation between 457.9 and 647.1 nm were studied. It was shown that the frequencies, intensities, and shapes of the bands related to the backbone stretching vibrations changed as the frequency of the exciting light varied. This was explained by a rather broad distribution of the conjugated segments of the polymer over the number of conjugated C=C bonds. A possible structural model involving atrans-cis conformation of the chain of the polymer studied was proposed.

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References

  1. P. P. Shorygin, and T. M. Ivanova,Dokl. Akad. Nauk SSSR, 1963,150, 533 [Dokl. Chem., 1963,150 (Engl. Transl.)].

    Google Scholar 

  2. H. Kuzmany,Phys. Stat. Solidi, 1980,B97, 521.

    Google Scholar 

  3. D. B. Fitchen,Mol. Cryst. Liq. Cryst., 1982,83, 95.

    Google Scholar 

  4. H. B. Schaffer, R. R. Chance, R. J. Silbey, K. Knoll, and R. R. Schrock,J. Chem. Phys., 1991,94, 4161.

    Google Scholar 

  5. Y. Yacoby and S. Roth,Synth. Metals, 1986,13, 299.

    Google Scholar 

  6. J. Tanaka, Y. Saito, M. Shimizu, and M. Tanaka,Synth. Metals, 1987,17, 307.

    Google Scholar 

  7. G. P. Brivio and E. Mulazzi,Phys. Rev.,B30, 876.

  8. V. V. Berdyugin, K. Ya. Burshtein, P. P. Shorygin, Yu. V. Korshak, A. V. Orlov, and M. A. Tlenkopachev,Dokl. Akad. Nauk SSSR, 1990,312, 379 [Dokl. Chem., 1990,312 (Engl. Transl.)].

    Google Scholar 

  9. D. Bloor,Chem. Phys. Lett, 1976,43, 270.

    Google Scholar 

  10. D. Bloor and O. Ronde,Chem. Phys. Lett., 1978,56, 244.

    Google Scholar 

  11. N. Sasaki, T. Masada, and T. Higashimura,Macromolecules, 1976,9, 664.

    Google Scholar 

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation

    V. V. Berdyugin, M. A. Tlenkopachev & P. P. Shorygin

Authors
  1. V. V. Berdyugin
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  2. M. A. Tlenkopachev
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  3. P. P. Shorygin
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Additional information

Translated fromIzvestiya Akademii Nauk. Serlya Khimkheskaya, No. 6, pp. 1173–1174, June, 1995.

The work was carried out with financial support of the Russian Foundation for Basic Research (Grant No. 93-03-5566) and the International Science Foundation (Grant No. 4895-0925)

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Berdyugin, V.V., Tlenkopachev, M.A. & Shorygin, P.P. On the structure of poly(2,4-dichlorophenylacetylene) from the data of resonance Raman spectra. Russ Chem Bull 44, 1133–1134 (1995). https://doi.org/10.1007/BF00707071

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  • DOI: https://doi.org/10.1007/BF00707071

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