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Reaction of ruthenium carbonylcarbide cluster Ru6C(CO)17 with nickelocene and pentamethylcyclopentadiene

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Abstract

The reaction of cluster Ru6C(CO)17 (1) with nickelocene is studied. Five CO ligands rather than a metal-ligand crown are substituted for two cyclopentadienyl groups to give a new complex Ru6C(η5-Cp)2(CO)12 (2). The reaction of cluster1 with entamethylcyclopentadiene leads to new complex Ru6C(μ-η1∶η5-CH2C5Me4)(CO)14 (3) containing the cr-bond CH2-Ru, along with an η5-coordinated cyclopentadienyl ring.

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References

  1. H. Vahrenkamp,Comments Inorg. Chem., 1985,4, 253.

    Google Scholar 

  2. T. A. Pakkanen, J. Pursianen, R. Venäläinen, and T. T. Pakkanen,J. Organomet. Chem., 1989,372, 129.

    Google Scholar 

  3. B. F. G. Johnson, R. D. Johston, and J. Lewis,J. Chem. Soc. A, 1968, 2865.

  4. B. F. G. Johnson, J. Lewis, and I. G. Williams,J. Chem. Soc. A, 1970, 901.

  5. M. Mlekuz, P. Bougeard, B. G. Sauer, R. Faggiani, C. J. L. Lock, M. J. McGlinchey, and G. Jaouen,Organometallics, 1985,4, 2046.

    Google Scholar 

  6. M. Mlekuz, P. Bougeard, M. J. McGlinchey, and G. Jaouen,J. Organomet. Chem., 1983,253, 117.

    Google Scholar 

  7. V. S. Kaganovich, V. A. Petrakova, and M. I. Rybinskaya,Izv. Akad. Nauk SSSR, Ser. Khim., 1990, 1893 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1990,39, 1720 (Engl. Transl.)].

    Google Scholar 

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    V. S. Kaganovich, Z. A. Kerzina, M. I. Rybinskaya & E. Kolehmainen

Authors
  1. V. S. Kaganovich
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  2. Z. A. Kerzina
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  3. M. I. Rybinskaya
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  4. E. Kolehmainen
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1171–1172, June, 1995.

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Kaganovich, V.S., Kerzina, Z.A., Rybinskaya, M.I. et al. Reaction of ruthenium carbonylcarbide cluster Ru6C(CO)17 with nickelocene and pentamethylcyclopentadiene. Russ Chem Bull 44, 1131–1132 (1995). https://doi.org/10.1007/BF00707070

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  • DOI: https://doi.org/10.1007/BF00707070

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