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Russian Chemical Bulletin

, Volume 44, Issue 6, pp 1127–1128 | Cite as

Effect of medium on the rate constant of decomposition of di(tert-butyl)trioxide

  • A. F. Khalizov
  • S. L. Khursan
  • V. V. Shereshovets
Brief Communications

Abstract

It was found that the medium affects the rate constant of the thermal decomposition of di(tert-butyl)trioxide. In all solvents studied, the decomposition occurred according to the first-order law. The effect of the solvent on the rate constant was analyzed within the framework of the Koppel-Palm equation.

Key words

trioxide chemiluminescence decomposition mechanism. 

References

  1. 1.
    P. D. Bartlett and P. Gunter,J. Am. Chem. Soc., 1966,88, 3288.Google Scholar
  2. 2.
    S. L. Khursan, V. V. Shereshovets, A. F. Khalizov, A. I. Voloshin, V. D. Komissarov, and V. P. Kazakov,React. Kinet. Catal. Lett, 1993,51, 389.Google Scholar
  3. 3.
    S. L. Khursan, V. V. Shereshovets, A. F. Khalizov, A. I. Voloshin, V. D. Komissarov, and V. P. Kazakov,Izv. Akad. Nauk, Ser. Khim., 1993, 2056 [Russ. Chem. Bull., 1993,42, 1968 (Engl. Transl.)].Google Scholar
  4. 4.
    V. V. Shereshovets, N. Ya. Shafikov, and F. A. Galieva,Izv. Akad. Nauk SSSR, Ser. Khim., 1982, 1177 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1982,31, 1050 (Engl. Transl.)].Google Scholar
  5. 5.
    R. F. Vasil'ev,Uspekhi Fiz. Nauk, 1966,89, 409 [Sov. Phys. Uspekhi, 1966,89 (Engl. Transl.)].Google Scholar
  6. 6.
    V. Pal'm,Osnovy kolichestvennoi teorii organicheskikh reaktsii [Bases of the Quantitative Theory of Organic Reactions], Khimiya, Leningrad, 1977 (in Russian).Google Scholar
  7. 7.
    A. Weissberger, E. Proskauer, J. Riddick, and E. Toops, Jr.,Organic Solvents, Interscience, New York, 1955.Google Scholar
  8. 8.
    Ya. Yu. Akhadov,Dielektricheskie svoistva chistykh zhidkostei [Dielectric Properties of Pure Liquids], Khimiya, Moscow, 1972 (in Russian).Google Scholar
  9. 9.
    Organic Peroxides, Ed. D. Swern, Wiley, New York, 1972, 27.Google Scholar

Copyright information

© Plenum Publishing Corporation 1995

Authors and Affiliations

  • A. F. Khalizov
    • 1
  • S. L. Khursan
    • 1
  • V. V. Shereshovets
    • 1
  1. 1.Institute of Organic ChemistryUfa Scientific Center of Ural Branch of the Russian Academy of SciencesUfaRussian Federation

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