Abstract
The peculiarities of radical copolymerization of styrene or acrylonitrile with triosmium carbonyl clusters whose ligand environments incorporate groups with multiple bonds capable of polymerization (4-vinylpyridine, allylamine, acrylic acid) are described. Using IR and NMR spectroscopy under the model conditions, it was shown that no side processes occur during the reaction of comonomers and azo-bis-isobutyronitrile, an initiator of radical polymerization. The cluster complex (the metal core and its ligand environment) is retained during copolymerization. The molecular weight characteristics of the copolymers obtained were studied. The double bonds in the cluster monomers mostly retain the properties inherent in their organic analogs.
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For part 42, seeIzv. Akad. Nauk, Ser. Khim., 1995 [Russ. Chem. Bull., 1995,44, 1056 (Engl. Transl.)].
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1102–1107, June, 1995.
The work was carried out with financial support from the International Science Foundation (Grant NJB 000).
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Bravaya, N.M., Pomogailo, A.D., Maksakov, V.A. et al. Preparation and reactivity of metal containing monomers. Russ Chem Bull 44, 1062–1067 (1995). https://doi.org/10.1007/BF00707053
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DOI: https://doi.org/10.1007/BF00707053