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Dynamics of contact radical ion pairs C60—aromatic amines. A study by picosecond laser photolysis

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Abstract

Charge transfer complexes between C60 and ternary aromatic amines (N,N,N,N′-tetramethyl-p-phenylenediamine,p-methoxy-N,N-dimethylaniline,p-methyl-N,N-dimethylaniline,N,N-diethylaniline,N,N-dimethylaniline, and triphenylamine) were studied in chlorobenzene solutions. The lifetimes of the excited state with charge transfer in these complexes were measured by the method of picosecond laser photolysis. The dependence of the rate constant of the back electron transfer on ΔG in the back electron transfer reaction with relaxation of the charge-transfer state exhibits the “Marcus-inverted” region.

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Authors and Affiliations

  1. Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation

    N. A. Nadtochenko, N. N. Denisov & P. P. Levin

Authors
  1. N. A. Nadtochenko
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  2. N. N. Denisov
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  3. P. P. Levin
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1078–1089, June, 1995.

The authors are grateful to D. V. Khudyakov and I. V. Rubtsov for help in experiments and to A. S. Lobach for the C60 supplied.

The work was financially supported by the Russian Foundation for Basic Research (Projects No. 93-03-05254 and 93-03-0217).

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Nadtochenko, N.A., Denisov, N.N. & Levin, P.P. Dynamics of contact radical ion pairs C60—aromatic amines. A study by picosecond laser photolysis. Russ Chem Bull 44, 1038–1049 (1995). https://doi.org/10.1007/BF00707050

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