Abstract
The kinetics of thermal decomposition of acetylcyclohexylsulfonyl peroxide is studied in an-decane solution in an oxygen atmosphere (303–333 K) and under anaerobic conditions (313–333 K); the reaction products are also studied in a cyclohexane solution under oxygenfree conditions (323 K). In the absence of oxygen, the reaction is found to proceedvia a chain-radical mechanism. Some kinetic parameters of the process are determined.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1049–1052, June, 1995.
This work was supported by the Russian Foundation for Basic Research (Project No. 93-03-5231).
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Zaripov, R.N., Safiullin, R.L., Yaubasarova, E.I. et al. Induced decomposition of acetylcyclohexylsulfonyl peroxide. Russ Chem Bull 44, 1011–1013 (1995). https://doi.org/10.1007/BF00707044
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DOI: https://doi.org/10.1007/BF00707044