Abstract
The changes in the structures of ammonium-exchanged forms of zeolite Y under conditions of prolonged exposure in air are studied by IR spectroscopy. It is established that the cation distribution in freshly prepared samples is nonequilibrium: the cations migrate with time to the most energetically stable sites. In addition, partial decomposition (no more than 3 to 6%) of the NH +4 -form is also observed, which results in a decrease in the ionic character of the framework bonds that is equivalent to an apparent increase in the framework silicate modulus.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1021–1024, June, 1995.
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Kosheleva, L.S., Shubaeva, M.A. Effect of “aging” of ammonium-exchanged forms of zeolite Y by IR spectroscopic data. Russ Chem Bull 44, 985–988 (1995). https://doi.org/10.1007/BF00707039
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DOI: https://doi.org/10.1007/BF00707039