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The crystal structures ofα,ω-diaminoalkane-cadmium(II) tetracyanonickelate(II) — Aromatic molecule inclusion compounds. VII: Three-dimensional host structures built ofcatena-[cadmium(II) tetra-μ-cyanonickelate(II)] layers and 1,3-diaminopropane, 1,5-diaminopentane or 1,7-diaminoheptane pillar

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Abstract

The crystal structures of four novel Hofmann-diam-type clathrates [Cd(tn)Ni(CN)4]·1.72(o-MeC6H4NH2),3-o, [Cd(tn)Ni(CN)4]·0.5(m-ClC6H4NH2),3-m, [Cd(daptn)Ni(CN)4]·1.5(p-MeC6H4NH2),5-p and [Cd(dahpn)Ni(CN)4]·1.5(2-MeC9H6N),7-q have been determined by single crystal X-ray diffraction method [tn:n=3, daptn:n=5, dahpn:n=7 for NH2(CH2) n NH2.3-o crystallizes in the monoclinic space groupP2/m,a=7.538(2),b=9.314(5),c=7.670(2) Å, β=91.03(2)°,Z=1,R=0.047 for 1252 reflections;3-m: orthorhombicPbam,a=12.1714(7),b=15.798(1),c=7.737(1) Å,Z=4,R=0.044 for 1871;5-p: monoclinicP21/a,a=13.736(3),b=22.014(4),c=7.762(3) Å, β=91.04(3)°,Z=4,R=0.047 for 5281; and7-q: orthorhombicPbam,a=13.599(2),b=27.938(4),c=7.619(2) Å,Z=4,R=0.054 for 3098. Their host structures are topologically the same to those of the previously reported Hofmann-diam-type clathrates: the two-dimensional [CdNi(CN)4]∞ networks are spanned by NH2(CH2) n NH2 at every Cd atom to build up the three-dimensional hosts. The number of cavities available for the guest is regulated by the deformation of the 2D networks and the diamine ligand in the host structure.

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Authors and Affiliations

  1. Department of Chemistry, College of Arts and Sciences, The University of Tokyo, Komaba, 153, Meguro, Tokyo, Japan

    Hidetaka Yuge, Miki Asai, Atsushi Mamada, Shin-Ichi Nishikiori & Toschitake Iwamoto

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  1. Hidetaka Yuge
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  2. Miki Asai
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  3. Atsushi Mamada
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  4. Shin-Ichi Nishikiori
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  5. Toschitake Iwamoto
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Additional information

Supplementary Data relating to this article are deposited with the British Library as Supplementary Publication No. SUP 82192 (37 pages).

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Yuge, H., Asai, M., Mamada, A. et al. The crystal structures ofα,ω-diaminoalkane-cadmium(II) tetracyanonickelate(II) — Aromatic molecule inclusion compounds. VII: Three-dimensional host structures built ofcatena-[cadmium(II) tetra-μ-cyanonickelate(II)] layers and 1,3-diaminopropane, 1,5-diaminopentane or 1,7-diaminoheptane pillar. J Incl Phenom Macrocycl Chem 22, 71–87 (1995). https://doi.org/10.1007/BF00706499

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  • DOI: https://doi.org/10.1007/BF00706499

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