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Asymmetric synthesis of organoelement analogs of natural products

17. Fluorine-containing esters ofS-homocysteic acid

  • Chemistry of Natural Compounds and Bioorganic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Michael addition of octafluoropentyl vinylsulfonate to complexes of Ni(II) with Schiffs bases derived from 5-2-N-(N-benzylprolyl)-o-aminobenzophenone and glycine orS-2-N-(N-benzylprolyl)-o-aminobenzaldehyde and alanine is a convenient preparative method for asymmetric synthesis of previously unknown fluorinated esters ofS-homocysteic acid.

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Authors and Affiliations

  1. Institute of Bioorganic and Petrochemistry, Ukrainian Academy of Sciences, 50 Khar'kovskoe sh., 253160, Kiev, Ukraine

    V. A. Soloshonok, N. Yu. Svistunova, V. P. Kukhar' & V. I. Popov

  2. A.N.Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    N. A. Kuz'mina & Yu. N. Belokon

Authors
  1. V. A. Soloshonok
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  2. N. Yu. Svistunova
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  3. V. P. Kukhar'
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  4. N. A. Kuz'mina
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  5. V. I. Popov
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  6. Yu. N. Belokon
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 786–790, April, 1993.

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Soloshonok, V.A., Svistunova, N.Y., Kukhar', V.P. et al. Asymmetric synthesis of organoelement analogs of natural products. Russ Chem Bull 42, 755–759 (1993). https://doi.org/10.1007/BF00704021

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  • DOI: https://doi.org/10.1007/BF00704021

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